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A 20-core copper(I) nanocluster as electron-hole recombination inhibitor on TiO nanosheets for enhancing photocatalytic H evolution. | LitMetric

AI Article Synopsis

Article Abstract

For the design of atom-precise copper nanoclusters, besides the exploration of their aesthetic cage-like architectures, their structural modulation and potential applications are being extensively explored. Herein, an atom-precise 20-core copper(I)-alkynyl nanocluster (UJN-Cu20) protected by ethinyloestradiol ligands issynthesized. By virtue of outer-shell hydroxyl groups, UJN-Cu20 could be uniformly modified on the surface of TiO nanosheets hydrogen bonding interactions, thus forming an efficient nanocomposite photocatalyst for hydrogen evolution. By constructing a Z-scheme heterojunction, the photocatalytic hydrogen evolution activity of the nanocomposite (13 mmol g h) significantly improved as compared to that of TiO nanosheets (0.4 mmol g h). As a narrow bandgap cocatalyst, UJN-Cu20 is confirmed to effectively inhibit the electron-hole recombination on the surface of the TiO nanosheet, which provides a new concept for the design of copper cluster-assisted effective photocatalysts.

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Source
http://dx.doi.org/10.1039/d1nr04683gDOI Listing

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