Two In-based organic-inorganic hybrid compounds with reversible phase transition derived from the order-disorder changes of cations or anions.

Solid-state phase transition materials have received extraordinary interest due to their rich physical properties, such as thermal, dielectric, and ferroelectric properties. Here, two In-based organic-inorganic hybrid compounds, (CHCHCHNH)[InBr(HO)] (1) and [(CH)N][InCl] (2), both display reversible phase transition and dielectric response. Differential scanning calorimetry measurements indicate that the phase transition temperatures () of 1 and 2 are 167 K and 351 K, respectively. Moreover, structural analyses disclose that the phase transition of 1 can be attributed to the order-disorder changes of phenethylammonium organic cations whereas the phase transition of 2 is caused by the order-disorder changes of [InCl] anions. The phase transitions of In-based organic-inorganic hybrid compounds can be driven by the order-disorder changes of cations or anions. Therefore, the system of In-based organic-inorganic hybrid compounds is very suitable for exploring organic-inorganic hybrid phase transition materials.