Fe clusters embedded on N-doped graphene as a photothermal catalyst for selective CO hydrogenation.

Chem Commun (Camb)

Instituto Universitario Mixto de Tecnología Química (CSIC-UPV), Universitat Politécnica de Valéncia (UPV), Avda. de los Naranjos s/n, Valencia, 46022, Spain.

Published: September 2021

In comparison with the Co analog, small Fe clusters incorporated in a graphene matrix exhibit a photo-assisted increase of 110% in reverse water gas shift CO hydrogenation under UV-Vis light irradiation. Available data indicate that the photo-assistance derives from light absorption by the N-doped graphene followed by charge recombination at the Fe clusters, increasing their local temperature.

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Source
http://dx.doi.org/10.1039/d1cc03524jDOI Listing

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