This article presents comparative data regarding the effect of foliar application of silicon dioxide and organosilicon compounds on soilless-grown Oak leaf lettuce (Lactuca sativa var. crispa). Data were derived from dry and fresh samples. Total nitrogen, total antioxidants capacity, total phenolic content, ascorbic acid, total pigments concentrations and growth parameters varied in response to the concentrations of the used preparations (silicon dioxide and organosilicon compounds). Capillary zone electrophoresis, spectrophotometry and coulometric analyzer were the principal involved methods. Data of total phenolic content, antioxidants capacity and ascorbic acid concentrations can provide physiological health benefits as functional foods along with an insight to plant stress physiology. Chlorophyll a and b concentrations, nitrogen content, dry matter content, plant height and fresh weights contribute to the understanding of physiological and biometric plants growth parameters.
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http://dx.doi.org/10.1016/j.dib.2021.107328 | DOI Listing |
Angew Chem Int Ed Engl
December 2024
Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Key Laboratory of Organosilicon Material Technology of Zhejiang Province, College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, 2318 Yuhangtang Road, Hangzhou, 311121, P. R. China.
In industry, the two important nitrile starting materials, adiponitrile and 2-methylglutaronitrile, are primarily manufactured through the well-known DuPont process, which consists of a tandem sequence including first hydrocyanation, isomerization and second hydrocyanation. However, this mature process has the intrinsic defects of step efficiency and regioselectivity. Herein, we report a nickel-catalyzed divergent, one-step double hydrocyanation of 1,3-butadiene to produce either adiponitrile or 2-methylglutaronitrile in high regioselectivity.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, P. R. China.
Transition metal-catalyzed ring opening and expansion reactions of silacyclobutanes (SCBs) constitute an atom- and step-economical strategy to construct value-added silicon-containing chemicals. Despite extensive studies, the reaction of SCBs with simple alkenes has only one precedent. Moreover, most reported reactions of SCBs use late transition metals (Pd, Ni, Rh) as catalysts.
View Article and Find Full Text PDFAcc Chem Res
December 2024
State Key Laboratory of Natural Medicines and Jiangsu Key Laboratory of Drug Discovery for Metabolic Diseases, Center of Advanced Pharmaceuticals and Biomaterials, China Pharmaceutical University, Nanjing 211198, China.
Int J Biol Macromol
December 2024
School of Materials Science and Engineering, Wuhan Textile University, Wuhan 430200, PR China; State Key Laboratory of New Textile Materials & Advanced Processing Technology, Wuhan Textile University, Wuhan 430073, PR China. Electronic address:
The discharge of oily wastewater not only pollutes waters but also deteriorates our living environment. Superhydrophobic cotton fabric is considered as an important remedy material for oily wastewater cleanup due to outstanding advantages including low cost, high porosity and switchable wettability. However, the existing superhydrophobic fabrics cannot exhibit durable superhydrophobicity during real-life applications due to poor interaction between the coatings and fabric substrates.
View Article and Find Full Text PDFAdv Sci (Weinh)
December 2024
Key Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou, 311121, China.
The photo-enzyme coupling system (PECS) holds immense potential in "green" biomanufacturing, encompassing the realms of pharmaceuticals, fuels, and carbon sequestration. Nevertheless, the intricate nature of enzymes' structures significantly impedes the seamless integration of multiple enzymes in a precise, tandem fashion, with exact control over their distribution, posing a formidable challenge. Herein, it has devised a mesoporous csq-type metal organic framework (Zr-MOF) from meso-tetrakis-(4-((phenyl)ethynyl)benzoate)porphyrin (Por-PTP) and Zr(μ-O)(μ-OH)(OH)(HO)) nodes (Zr clusters), featuring intricate hierarchical hexagonal (5.
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