Herein, for the first time the carbon dots (CDs) were synthesized by reflux method from sawmill waste material. We also represent a novel strategy based on fluorescent CDs for determination of ponceau 4R and allura red dyes in soft drinks. Interestingly, both the dyes were sensitive and showed effective fluorescence quenching of the CDs owing to the interaction between them. The analytical applicability of CDs were evaluated for detection of both the dyes with a good linear relationship between the concentration range of 0.0 to 3.0 µg mL and having detection limit 0.45 and 0.47 µg mL for allura red and ponceau 4R dyes respectively. Meanwhile, the potential application of this novel fluorescent probe for dyes determination in real samples was validated in different soft drink samples with good accuracy and precision. Thus, these findings provides new insights for the potential risk assessment of both the dyes. Moreover, CDs acted as an excellent fluorescent material in cellular imaging owing to their cellular uptake and localization.
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http://dx.doi.org/10.1038/s41598-021-97552-5 | DOI Listing |
Bull Environ Contam Toxicol
September 2024
Hygiene-Institut des Ruhrgebiets, Rotthauser Str. 21, Gelsenkirchen, D-45879, Germany.
Coastal ecosystems are characterized by various human activities with potential adverse impacts. This study aimed to evaluate the potential oxidative stress effects in representative aquatic biota deployed in situ at a sawmill wastes dump (test site) and reference site in a coastal ecosystem for a short term (28 days) period. PAHs and OCPs were analysed using GC-FID and GC-MS respectively in surface water and sediments.
View Article and Find Full Text PDFEnviron Pollut
September 2023
Department of Earth Sciences, Uppsala University, Box 256, SE-751 05, Uppsala, Sweden.
Deposits of contaminated wood fiber waste (fiberbanks), originating from sawmills and pulp and paper industries, have been found in the aquatic environment in boreal countries. In-situ isolation capping has been proposed as a remediation solution because it has the potential to prevent dispersal of persistent organic pollutants (POPs) from this type of sediment. However, knowledge about the performance of such caps when placed on very soft (unconsolidated), gaseous organic rich sediment is scarce.
View Article and Find Full Text PDFJ Environ Manage
August 2023
Department of Sanitary and Environmental Engineering, Federal University of Santa Catarina, Florianópolis, 88040-970, Santa Catarina, Brazil.
Waste valorization is mandatory to develop and consolidate a circular bioeconomy. It is necessary to search for appropriate processes to add value to different wastes by utilizing them as feedstocks to provide energy, chemicals, and materials. For instance, hydrothermal carbonization (HTC) is an alternative thermochemical process that has been suggested for waste valorization aiming at hydrochar production.
View Article and Find Full Text PDFMolecules
October 2022
Department of Pharmaceutical and Pharmacological Sciences, University of Padova, Via Marzolo 5, 35131 Padova, Italy.
Secondary metabolites from the sawmill waste bark were extracted using an innovative two-step extraction that includes a first step with supercritical CO (SCO) and a second step using green solvents, namely ethanol, water, and water ethanol mixture. Maceration (M), ultrasound assisted extraction (UAE) and microwave assisted extraction (MAE) techniques were applied in the second step. A total of nineteen extract were obtained and yield were compared.
View Article and Find Full Text PDFACS Appl Mater Interfaces
May 2022
Laboratory of Natural Materials Technology, Åbo Akademi University, Henrikinkatu 2, FI-20500 Turku, Finland.
This work presents a new approach for more effective valorization of sawmill wastes (Beech and Cedar sawdusts), which were used as new sources for the extraction of lignin-containing and lignin-free cellulose II nanocrystals (L-CNCs and CNCs). It was shown that the properties of the extracted nanocrystals depend on the nature of the used sawdust (softwood or hardwood sawdusts). L-CNCs and CNCs derived from Beech fibers were long and thin and also had a higher crystallinity, compared with those obtained from Cedar fibers.
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