Our previous work has shown that for cardiac applications, combining low-temperature plasma oxidation with an amorphous carbon coating (a-C:N:H type) constitutes a prospective solution. In this study, a short-term modification by low-temperature oxygen plasma is proposed as an example and a method for shaping the topography and surface energy of the outer amorphous carbon coating, produced via the Radio-Frequency Chemical Vapour Deposition (RFCVD) method on NiTi alloy oxidized under glow-discharge conditions. This treatment alters the chemical composition of the outer zone of the surface layer. A slight increase is also noted in the surface roughness at the nanoscale. The contact angles were shown to increase by about 20% for water and 30% for diiodomethane, while the surface free energy decreased by ca. 11%. The obtained results indicate that even short-term contact with low-temperature plasma can shape the surface properties of the carbon coating, an outcome which shows potential in terms of its use in medical applications.
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http://dx.doi.org/10.3390/ma14174842 | DOI Listing |
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January 2025
Department of Civil and Environment Engineering, University of Ulsan, Daehakro 93, Namgu, Ulsan, 44610, Republic of Korea.
The current lack of stable, scalable, and efficient coating technology dramatically limits the exploitation of solar-driven graphitic carbon nitride (CN) photocatalysts. Herein, a unique, efficient, and scalable method is reported to immobilize CN powder on various substrates ranging from Fluorine tin oxide (FTO), glass, Plexiglas, Al foil, Ti foil, and Granite stone, to even wood. The film shows an outstanding thickness of 212 µm, which is the highest value ever reported.
View Article and Find Full Text PDFACS Omega
January 2025
Groundwater Protection Unit, Environmental Department, Saudi Aramco, P.O. Box1977, Dhahran 31311, Saudi Arabia.
Methyl tertiary-butyl ether (MTBE) and BTEX (benzene, toluene, ethylbenzene, and xylenes) are common groundwater contaminants that pose significant health risks. This study investigated the efficiency of a colloidal activated carbon (CAC) material in removing MTBE and BTEX from contaminated water using batch and continuous core flooding systems. In the batch system, a mixture of sand and carbonate was coated with 1-3 g of CAC for the removal of contaminants.
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January 2025
Department of Chemical Engineering, Istanbul Technical University, Istanbul 34469, Türkiye.
In this study, a bovine serum albumin (BSA)-coated magnetic single-walled carbon nanotube (mCNT) was synthesized using covalent functionalization. Mitoxantrone (MTO) was chosen as a model drug, and loading/release profiles of mCNTs were evaluated. To synthesize BSA-coated mCNT, 1-ethyl-3-(3-(dimethylamino)propyl) carbodiimide and -hydroxysuccinimide were used as cross-linking agents.
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January 2025
Department of Biotechnology, Manipal Institute of Technology, Manipal Academy of Higher Education, Manipal, Karnataka 576104, India.
The presence of chlorinated compounds in water resources presents various environmental and health risks. Therefore, there is a precise need to develop a potential technique for fast and efficient monitoring of chlorinated contaminants in water due to environmental protection and regulation compliance. Here, we designed a paper-based thin-film solid-phase microextraction (TF-SPME) patch to estimate 4-chlorophenol (4-CRP), a widely known environmentally hazardous pollutant in water samples.
View Article and Find Full Text PDFJ Environ Manage
January 2025
Mechatronics Engineering Department, School of Automobile, Mechanical and Mechatronics, Manipal University Jaipur, India. Electronic address:
Herein, novel hollow ZnO and ZnO@SnInS core-shell nanorods (NRs) with controlled shell thickness were developed via a facile synthesis approach for the efficient photocatalytic remediation of organic as well inorganic water pollutants. The introduction of SnInS shell layer coating over ZnO enhances visible light absorption, efficient exciton-mediated direct charge transfer, and reduces the band gap of ZnO@SnInS core-shell nanorods. The ZnO@SnInS core-shell nanorods show efficient solar-light driven catalytic efficiency for the disintegration of industrial dye (orange G), degradation of tetracycline, and reduction of hazardous Cr (VI) ions in aquatic systems.
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