Carbon Nanostructures Doped with Transition Metals for Pollutant Gas Adsorption Systems.

Molecules

Instituto de Física, Universidad Nacional Autónoma de Mexico, Apartado Postal 20-364, Ciudad de México 01000, Mexico.

Published: September 2021

The adsorption of molecules usually increases capacity and/or strength with the doping of surfaces with transition metals; furthermore, carbon nanostructures, i.e., graphene, carbon nanotubes, fullerenes, graphdiyne, etc., have a large specific area for gas adsorption. This review focuses on the reports (experimental or theoretical) of systems using these structures decorated with transition metals for mainly pollutant molecules' adsorption. Furthermore, we aim to present the expanding application of nanomaterials on environmental problems, mainly over the last 10 years. We found a wide range of pollutant molecules investigated for adsorption in carbon nanostructures, including greenhouse gases, anticancer drugs, and chemical warfare agents, among many more.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8434604PMC
http://dx.doi.org/10.3390/molecules26175346DOI Listing

Publication Analysis

Top Keywords

carbon nanostructures
12
transition metals
12
metals pollutant
8
gas adsorption
8
adsorption
5
carbon
4
nanostructures doped
4
doped transition
4
pollutant gas
4
adsorption systems
4

Similar Publications

In this study, we present an intelligent electromagnetic-actuated microfluidic chip integrated with a G-quadruplex DNAzyme-based biocatalysis platform for rapid and sensitive tetracycline (TC) detection. In this sensing system, TC significantly quenches fluorescent magnetic carbon dots (M-CDs) via the internal filtration effect and dynamic quenching (the excitation and emission wavelength at 350 and 440 nm, respectively). Then, the G-quadruplex on the M-CDs-Aptamer is exposed and bound with hemin to form hemin-G-quadruplex DNAzyme, catalyzing the conversion of 3,3',5,5'-tetramethylbenzidine to produce blue color.

View Article and Find Full Text PDF

Temperature-Dependent Formation of Carbon Nanodomains in Silicon Oxycarbide Glass-A Reactive Force Field MD Study.

J Phys Chem C Nanomater Interfaces

January 2025

Institute of General, Inorganic and Theoretical Chemistry Center for Chemistry and Biomedicine, University of Innsbruck, Innrain 80-82, A-6020 Innsbruck, Austria.

Novel anode materials for lithium-ion batteries (LIBs) are constantly being explored to further improve battery performance. In this work, ReaxFF molecular dynamics (MD) simulations are performed to model the early stages in the synthesis of nanostructured silicon carbide (SiC), which is one such promising material. The focus lies on its precursor, silicon oxycarbide glass of composition (SiOC) (17 mol% Si, 28 mol% O, and 54 mol% C), in the following referred to as SiOC.

View Article and Find Full Text PDF

Scaling of steel surfaces, prevalent in various industrial applications, results in significant operational inefficiencies and maintenance costs. Inspired by the natural hydrophobicity of springtail (Collembola) skin, which employs micro- and nanostructures to repel water, we investigate the application of silicone nanofilaments (SNFs) as a coating on steel surfaces to mitigate scaling. Silicone nanofilaments, previously successful on polymers, textiles, and glass, are explored for their hydrophobic properties and stability on steel.

View Article and Find Full Text PDF

Mercury ions (Hg) seriously harm the central nervous system of humans, leading to brain damage and even heart failure and death. Therefore, effective detection of Hg in water quality has become an urgent research field. It is very important to develop economically efficient fluorescent sensors to achieve rapid and sensitive detection of Hg.

View Article and Find Full Text PDF

Gold-based (Au) nanostructures are efficient catalysts for CO oxidation, hydrogen evolution (HER), and oxygen evolution (OER) reactions, but stabilizing them on graphene (Gr) is challenging due to weak affinity from delocalized [Formula: see text] carbon orbitals. This study investigates forming metal alloys to enhance stability and catalytic performance of Au-based nanocatalysts. Using ab initio density functional theory, we characterize [Formula: see text] sub-nanoclusters (M = Ni, Pd, Pt, Cu, and Ag) with atomicities [Formula: see text], both in gas-phase and supported on Gr.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!