AI Article Synopsis
- The study examined how α-hydroxy acids like L-Tartaric acid and L-Malic acid form complexes with d-electron metal ions (copper, cobalt, nickel) in aqueous solutions.
- Potentiometric measurements and computer analysis were used to determine the stability constants of these complexes.
- Spectroscopic methods (EPR, UV-Vis, CD, IR) revealed that dimers form with copper(II) ions while monomers form with cobalt(II) and nickel(II) ions.
Article Abstract
Binary complexes of α-hydroxy acids (L-Tartaric acid and L-Malic acid) with d-electron metal ions (copper, cobalt, nickel) were investigated. Potentiometric measurements have been performed in aqueous solution with computer analysis of the data for determination of the stability constants of complexes formed in the studied systems. The coordination mode of the complexes was defined using spectroscopic methods: electron paramagnetic resonance (EPR), ultraviolet-visible (UV-Vis), circular dichroism (CD), and infrared (IR). Results of the equilibrium studies have provided evidence for the formation of dimers with copper(II) ions and monomers with cobalt(II) and nickel(II) ions.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8433706 | PMC |
| http://dx.doi.org/10.3390/molecules26175290 | DOI Listing |
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