This review presents an overview of the use of organic functionalized carbon nanostructures (CNSs) in solar energy conversion schemes. Our attention was focused in particular on the contribution of organic chemistry to the development of new hybrid materials that find application in dye-sensitized solar cells (DSSCs), organic photovoltaics (OPVs), and perovskite solar cells (PSCs), as well as in photocatalytic fuel production, focusing in particular on the most recent literature. The request for new materials able to accompany the green energy transition that are abundant, low-cost, low-toxicity, and made from renewable sources has further increased the interest in CNSs that meet all these requirements. The inclusion of an organic molecule, thanks to both covalent and non-covalent interactions, in a CNS leads to the development of a completely new hybrid material able of combining and improving the properties of both starting materials. In addition to the numerical data, which unequivocally state the positive effect of the new hybrid material, we hope that these examples can inspire further research in the field of photoactive materials from an organic point of view.
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http://dx.doi.org/10.3390/molecules26175286 | DOI Listing |
Angew Chem Int Ed Engl
January 2025
Nankai University, College of Chemistry, 94 Weijin Road, 300071, Tianjin, CHINA.
Cyclopropanes are prevalent in natural products, pharmaceuticals, and bioactive compounds, functioning as a significant structural motif. Although a series of methods have been developed for the construction of the cyclopropane skeleton, the development of a direct and efficient strategy for the rapid synthesis of cyclopropanes from bench-stable starting materials with a broad substrate scope and functional group tolerance remains challenging and highly desirable. Herein, we present an electrochemical method for the direct cyclopropanation of unactivated alkenes using active methylene compounds.
View Article and Find Full Text PDFChemistry
January 2025
Université de Rennes 1, Chemistry, Equipe CORINT, Institut des Sciences Chimiques de Rennes, Université de Rennes 1 - UMR 6226 CNRS, Bâtiment 10A, Bureau 158, Avenue du Général Leclerc, 35042, Rennes, FRANCE.
Capozzi's groundbreaking work in 1982 introduced a fascinating reaction involving highly reactive tertiary aliphatic cations and silylated alkynes. This reaction provided an innovative solution to the challenge of coupling a fully substituted tertiary aliphatic fragment with an alkyne moiety. Building upon Capozzi's pioneering efforts, we started an extensive exploration of reaction conditions to expand the initial scope of this reaction.
View Article and Find Full Text PDFMetabolomics
January 2025
Laboratory of Organic Chemistry, Wageningen University & Research, 6708 WE, Wageningen, the Netherlands.
Introduction And Objective: Rumex sanguineus, a traditional medicinal plant of the Polygonaceae family, is gaining popularity as an edible resource. However, despite its historical and nutritional significance, its chemical composition remains poorly understood. To deepen the understanding of the of Rumex sanguineus composition, an in-depth analysis using non-targeted, mass spectrometry-based metabolomics was performed.
View Article and Find Full Text PDFEnviron Geochem Health
January 2025
School of Planning, Design and Construction, Michigan State University, East Lansing, MI, 48824, USA.
Polychlorinated biphenyls (PCBs) are persistent organic pollutants emitted during e-waste activities. Upon release into the environment, PCBs can pose harmful effects to the humans and environment. The present review focused on the effects of PCBs on cell proliferation, apoptosis, functional and developmental toxicity and potential possible molecular mechanisms upon cells and stem cells.
View Article and Find Full Text PDFJ Chem Ecol
January 2025
Department of Biological Sciences, University of South Carolina, Columbia, SC, USA.
Plants emit green leaf volatiles (GLVs) in response to biotic and abiotic stress. Receiver plants perceive GLVs as alarm cues resulting in activation of defensive or protective mechanisms. While this is well documented, it is not known how GLVs are perceived by receiver cells and what the structural determinants are for GLV activity.
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