A Zn-S aqueous primary battery with high energy and flat discharge plateau.

Chem Commun (Camb)

Key Laboratory for Macromolecular Science of Shaanxi Province, Shaanxi Engineering Laboratory for Advanced Energy Technology, School of Materials Science and Engineering, Shaanxi Normal University, Xi'an, Shaanxi 710062, P. R. China.

Published: September 2021

We demonstrate a disposable aqueous primary battery chemistry that comprises environmentally benign materials of the sulfur cathode and Zn anode in a 1 M ZnCl aqueous electrolyte. The Zn-S battery shows a high energy density of 1083.3 Wh kg for sulphur with a flat discharge voltage plateau around 0.7 V. When operating at a high mass loading of 8.3 mg cm for sulfur in the cathode, the battery exhibits a very high areal capacity of 11.4 mA h cm and areal energy of 7.7 mW h cm.

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http://dx.doi.org/10.1039/d1cc04337dDOI Listing

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