A facile and green -glycosylation method has been developed featuring protecting-group-free and proceeding-in-water like enzymatic synthesis. Glycosylation of fluoride donors with thiol sugar acceptors using Ca(OH) as a promoter afforded various thioglycosides in good yields with exclusive stereoselectivity. This method also enabled the successful production of -linked oligosaccharides and -linked glycopeptides.
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|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8423405 | PMC |
| http://dx.doi.org/10.1039/D1GC00098E | DOI Listing |
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