α-Substituted peroxides have been found in natural products and are widely used as anti-malarial agents. Zn(OTf) -catalyzed peroxidation of 1,3,5-triazines has been developed, accessing diversely substituted α-amino tertiary alkylperoxides with high efficiency. Mechanistic investigations and useful synthetic application of the products have also been presented.
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| http://dx.doi.org/10.1002/asia.202100833 | DOI Listing |
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