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Nickel cyclotetraphosphate grown on carbon cloth (NiPO/CC) is synthesized an anion exchange reaction method and it shows excellent hydrogen evolution reaction (HER) activity and strong working stability in acid due to the merits of its unique polymer-like structure, mesoporous characteristics, and superhydrophilic surface.

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http://dx.doi.org/10.1039/d1dt02194jDOI Listing

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Nickel cyclotetraphosphate grown on carbon cloth (NiPO/CC) is synthesized an anion exchange reaction method and it shows excellent hydrogen evolution reaction (HER) activity and strong working stability in acid due to the merits of its unique polymer-like structure, mesoporous characteristics, and superhydrophilic surface.

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A porous nickel cyclotetraphosphate nanosheet as a new acid-stable electrocatalyst for efficient hydrogen evolution.

Nanoscale

May 2018

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, International School of Materials Science and Engineering, Wuhan University of Technology, Luoshi Road 122, Wuhan, 430070, Hubei, China.

The stability of non-precious metal-based electrocatalysts for the acidic hydrogen evolution reaction (HER) is of great importance. Here, we have used nickel cyclotetraphosphate (Ni2P4O12) nanosheet arrays as a HER electrocatalyst for the first time. The Ni2P4O12 arrays were obtained through a facile low-temperature phosphorylation process and possess superior HER catalytic activities and stability in acid.

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