Promising heterofunctional ()-9-azabicyclo[4.2.1]nona-2,4-dienes (79-92%) and 9-azabicyclo[4.2.1]nona-2,4,7-trienes (77-90%) containing a cholesterol fragment in the structure have been synthesized for the first time through the [6π + 2π] cycloaddition reaction of terminal 1,2-dienes and symmetric 1,3-diynes with -carbocholesteroxyazepine under the action of the Co(acac)(dppe)/Zn/ZnI three-component catalytic system.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8388074 | PMC |
| http://dx.doi.org/10.1021/acsomega.1c03321 | DOI Listing |
Publication Analysis
Top Keywords
[6π 2π]
8
2π] cycloaddition
8
13-diynes -carbocholesteroxyazepine
8
cobalti-catalyzed [6π
4
cycloaddition 12-dienes
4
12-dienes 13-diynes
4
-carbocholesteroxyazepine synthesis
4
synthesis undescribed
4
undescribed heterofunctional
4
heterofunctional 9-azabicyclo[421]nonaditrienes
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!