Severity: Warning
Message: file_get_contents(https://...@gmail.com&api_key=61f08fa0b96a73de8c900d749fcb997acc09): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests
Filename: helpers/my_audit_helper.php
Line Number: 143
Backtrace:
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 143
Function: file_get_contents
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 209
Function: simplexml_load_file_from_url
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 994
Function: getPubMedXML
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3134
Function: GetPubMedArticleOutput_2016
File: /var/www/html/application/controllers/Detail.php
Line: 574
Function: pubMedSearch_Global
File: /var/www/html/application/controllers/Detail.php
Line: 488
Function: pubMedGetRelatedKeyword
File: /var/www/html/index.php
Line: 316
Function: require_once
The Haber-Bosch process for ammonia (NH ) production in industry relies on high temperature and high pressure and is therefore highly energy intensive. In addition, the activity of the solid transition metal-based catalysts used is typically limited by the scaling relation between activation barrier for N dissociation and nitrogen-binding energy. Here, an innovative Li-based loop in a liquid alloy-salt catalytic system for ambient-pressure NH synthesis from N and H was developed. The looping process consisted of three reaction steps taking place simultaneously. The first step was the nitrogen fixation by Li in the liquid Li-Sn alloy to form lithium nitride (Li N), which floated up and dissolved into the molten salt. The second step was the hydrogenation of the Li N to produce NH and lithium hydride (LiH) in the molten salt. The third step was the decomposition of the LiH to regenerate Li in the presence of Sn. An average NH yield rate of 0.025 μg s was achieved in an 81 h test at 510 °C and ambient pressure. The floating and dissolution of Li N realized in the liquid catalytic system enabled circumventing the scaling relation exerted on Li, and the remarkable properties of liquid alloy and molten salt offered extraordinary advantages for NH synthesis at ambient pressure.
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Source |
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http://dx.doi.org/10.1002/cssc.202101571 | DOI Listing |
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