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Anal Chim Acta
May 2025
Department of Chemical Engineering and Analytical Chemistry, University of Barcelona, Av. Diagonal 645, Barcelona, E-08028, Spain.
Background: Ambient Mass Spectrometry (AMS) encompasses a group of techniques that have emerged as powerful strategies for direct, in-situ and high-throughput analysis, also in compliance with the principles of green analytical chemistry. Swab Touch Spray-Mass Spectrometry (Swab TS-MS) is a home-made AMS technique that involves the use of a medical swab as sampling tool and electrospray probe. To date, Swab TS-MS has been applied only for the analysis of small molecules, especially in forensic and medical fields, leaving the analysis of peptides and proteins still unexplored.
View Article and Find Full Text PDFEnviron Pollut
March 2025
College of Animal Science and Technology, Inner Mongolia Minzu University, Tongliao, Inner Mongolia, 028000, China; Inner Mongolia Key Laboratory of Toxicant Monitoring and Toxicology. Electronic address:
Global warming causes the release of dioxin-like deposits and increases geographical migration, increasing the risk of exposure for humans and animals. In this experiment, we used CYP1A transgenic zebrafish Tg (cyp1a: mCherry) and liver fluorescent transgenic zebrafish Tg (fabp10: Ps Red) as an animal model and exposed to 2,3,7,8-Tetrachlorodibenzo-p-Dioxin (TCDD) at 26 °C and 30 °C, respectively. Morphological changes, histological changes, transcriptome and related genes expression were detected.
View Article and Find Full Text PDFJ Colloid Interface Sci
March 2025
School of Materials Science and Engineering, Changsha University of Science & Technology, Changsha 410114, China.
Integrating energy donor and acceptor chromophores as ligands within one MOF for advanced artificial photosynthesis is of great interest but appears to be a major challenge. Herein, via a simple one-pot synthetic strategy, an energy acceptor porphyrin ligand 5,15-di(p-benzoato)porphyrin (HDPBP) was successfully integrated into an energy donor 1,4-naphthalenedicarboxylic acid (HNDC)-based MOF (UiO-66-NDC) to construct a mixed-ligand MOF, donated as UiO-66-NDC-HDPBP. Benefiting from the ample overlap between the emission spectrum of HNDC and the absorption spectrum of HDPBP, an efficient energy transfer (EnT) process from the donor HNDC to the acceptor HDPBP within UiO-66-NDC-HDPBP can occur and be captured by time-resolved spectroscopy.
View Article and Find Full Text PDFJ Colloid Interface Sci
March 2025
Key Laboratory of Marine Environment and Ecology, Ministry of Education, Qingdao 266100, China; Shandong Provincial Key Laboratory of Marine Environment and Geological Engineering (MEGE), Qingdao 266100, China; College of Environmental Science and Engineering, Ocean University of China, Qingdao 266100, China. Electronic address:
In recent years, zero-valent aluminum (ZVAl) has attracted significant attention as a novel material in the field of water treatment. However, its high reactivity leads to rapid aging when exposed to air, limiting its preservation and practical utilization. To address this issue, carbon materials modified ZVAl (C@ZVAl) were prepared by mechanical ball-milling to improve the aging resistance of ZVAl.
View Article and Find Full Text PDFWe report the cosolvency effect of formamidinium lead triiodide (FAPbI) in a mixture of γ-butyrolactone (GBL) and 2-methoxyethanol (2ME), a phenomenon where FAPbI shows higher solubility in the solvent blend than in either alone. We found that FAPbI exhibits 10× higher solubility in 30% 2ME in GBL than in 2ME alone and 40% higher solubility than in GBL alone at 90 °C. This enhanced solubility is attributed to the disruption of the hydrogen bonding network within 2ME, allowing its hydroxyl and ether groups to interact more freely with the solute.
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