AI Article Synopsis
- * Formation of liquid crystalline phases relies on unique face-to-face π-π interactions between the dendritic molecules, which is uncommon.
- * This review focuses on adjusting these π-π interactions to control the creation of liquid crystalline phases through smart molecular design.
Article Abstract
Most triazine-based liquid crystalline (LC) dendrimers reported thus far are the main-chain LC macromolecules with long flexible chains at their periphery and attached to internal rigid or semi-rigid frameworks. Their formation of mesogenic phases often depends on the intermolecular face-to-face π-π interactions between dendritic molecules, which are unusual. Their mesogenic phases can also be formed by incorporation of mesogenic units to the dendritic skeletons through long flexible chains, as most side-chain LC dendrimers, in which the peripheral mesogenic units generally play the important roles. For main-chain triazine-based dendrimers, their morphology is maintained by restricted freedom of rigid or semi-rigid connecting units, and their formations of LC phases are therefore not straightforward to be controlled. In this review, we thus describe modulating of the intermolecular face-to-face π-π interactions between the triazine-based dendritic molecules, with the aim of forming LC phases through molecular design.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8399522 | PMC |
| http://dx.doi.org/10.3390/nano11082112 | DOI Listing |
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