Visible Light-Driven GO/TiO-CA Nano-Photocatalytic Membranes: Assessment of Photocatalytic Response, Antifouling Character and Self-Cleaning Ability.

Photocatalysis and membrane technology in a single unit is an ideal strategy for the development of wastewater treatment systems. In this work, novel GO (x wt%)/TiO-CA hybrid membranes have been synthesized via a facile non-solvent induced phase inversion technique. The strategy aimed to address the following dilemmas: (1) Effective utilization of visible light and minimize e/h recombination; (2) Enhanced separation capability and superior anti-fouling and self-cleaning ability. The experimental results reveal that the integration of nano-composite (GO/TiO) boosts the membrane properties when compared to pristine CA and single photocatalyst employed membrane (GO-CA and TiO-CA). The effect of GO content on the properties of the photocatalytic membrane has been determined by utilizing three different ratios of GO, viz. 0.5 wt%, 1 wt%, and 2 wt% designated as NC(1)-CA, NC(2)-CA, and NC(3)-CA, respectively. Amongst them, NC(3)-CA membrane showed state-of-the-art performance with an elevated photocatalytic response (four times higher than pristine CA membrane) toward methyl orange. Moreover, the water flux of NC(3)-CA membrane is 613 L/mh, approximately three times higher than bare CA membrane (297 L/mh), while keeping the MO rejection high (96.6%). Besides, fouling experiments presented the lowest total and fouling resistance ratios and a higher flux recovery ratio (91.78%) for the NC(3)-CA membrane, which endows the membrane with higher anti-fouling and self-cleaning properties. Thus, NC(3)-CA membrane outperforms the other as synthesized membranes in terms of separation efficiency, visible light photo-degradation of pollutant, anti-fouling and self-cleaning ability. Therefore, NC(3)-CA membrane is considered as the next generation membrane for exhibiting great potential for the wastewater treatment applications.