Technical design and optimisation of polymer inclusion membranes (PIMs) for sample pre-treatment and passive sampling - A review.

This review reports on the increasing interest in technical designs, calibration, and application of PIM-based devices in sample pre-treatment and passive sampling in environmental water monitoring from 2010 to 2021. With regards to passive sampling, devices are calibrated in a laboratory setup using either a dip-in or flow-through approach before environmental application. In sample preparation, the device set-ups can be offline, online or in a continuous flow separation device connected to a flow injection analysis system. The PIMs have also demonstrated potential in both these offline and online separations; however, there is still a draw-back of low diffusion coefficients obtained in these PIM set-ups. Electro-driven membrane (EME) extraction has demonstrated better performance as well as improved analyte flux. Critical in electro-driven membrane extraction is applying correct voltage that may not compromise the PIM performance due to leaching of components to the aqueous solutions. Further, besides different PIM configurations and designs being developed, PIM based extractions are central to PIM components (base polymer, carrier and plasticizer). As such, recent studies have also focused on improving PIM stability by investigating use of various PIM components, incorporating nano additives into the PIM composition, and investigating novel green PIM synthetic routes. All these aspects are covered in this review. Further, some recent studies that have demonstrated the ability to eliminate effects of flow patterns and membrane biofouling in PIM based applications are also included.