One of the most important environmental and health issues today is the elimination of the dye pollution from the contaminated water ecosystem. The use of geopolymers to eliminate such contaminants has recently emerged as a promising alternative. In this study, metakaolin based geopolymer (MKBG) was synthesized to be a promising adsorbent for Basic Blue 7 (BB7). To optimize the input parameters (solution pH, MKBG dose, mixing time, temperature, mixing speed, column diameter, and flow rate) towards BB7 removal by MKBG, a Box-Behnken design (BBD) was employed to develop the response model, followed by numerical optimization. The quadratic models correlating the adsorption variables to BB7 adsorption yield as responses were developed for batch and dynamic flow systems. The pseudo-second-order model accurately predicted the BB7 adsorption kinetics on MKBG. Decolorization yields of BB7 in batch and continuous systems reached 96 % and 56 %, respectively. The Langmuir model accurately described equilibrium data, thereby justifying monolayer and homogeneous adsorption. The MKBG demonstrated significant reusability up to 20 dynamic flow adsorption cycles. IR, SEM, and zeta potential measurements were used to describe the sorbent structure, and the mechanism of MKBG-BB7 interaction was assessed. Overall, MKBG offers a good application potential for the treatment of basic dye contaminated waters.
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http://dx.doi.org/10.1016/j.jenvman.2021.113548 | DOI Listing |
Sci Rep
January 2025
China University of Mining and Technology (Beijing), Beijing, 100083, China.
This study aims to evaluate the efficiency and energy release characteristics of different types of coal in pulse detonation engines (PDE) to advance the development of deep coal fluidization detonation technology, achieving more efficient and cleaner coal utilization. Using a custom PDE setup, experiments were conducted with four coal types at mass flow rates from 30 to 120 g/s. High-frequency pressure sensors assessed pressure dynamics and detonation wave propagation, complemented by numerical simulations for accuracy.
View Article and Find Full Text PDFInt J Pharm
January 2025
Department of Chemical and Biochemical Engineering, Rutgers University, Piscataway, NJ, 08854, USA; Center for Structured Organic Particulate Systems (C-SOPS), Cranbury, NJ, 08512, USA.
This study used Raman and near-infrared (NIR) spectroscopy to monitor small real-time changes in powder blends and tablets in low-dose pharmaceutical formulations. The research aims to enhance process analytical technology (PAT) in pharmaceutical manufacturing, ensuring high-quality and uniform products with applications to produce drugs with narrow therapeutic indices (NTI). The study utilizes Raman and NIR spatially resolved spectroscopy (SRS) techniques to monitor a moderate cohesive material's active pharmaceutical ingredient (API) concentrations during manufacturing.
View Article and Find Full Text PDFJ Autism Dev Disord
January 2025
Center for Child Health, Behavior and Development, Seattle Children's Research Institute, 1920 Terry Ave CURE-3, Seattle, WA, 98101, USA.
Purpose: Dynamic eye-tracking paradigms are an engaging and increasingly used method to study social attention in autism. While prior research has focused primarily on younger populations, there is a need for developmentally appropriate tasks for older children.
Methods: This study introduces a novel eye-tracking task designed to assess school-aged children's attention to speakers involved in conversation.
Breast Cancer Res
January 2025
Division of Medical Oncology, The Ohio State University Comprehensive Cancer Center, Columbus, OH, USA.
Background: Epidemiological studies associate an increase in breast cancer risk, particularly triple-negative breast cancer (TNBC), with lack of breastfeeding. This is more prevalent in African American women, with significantly lower rate of breastfeeding compared to Caucasian women. Prolonged breastfeeding leads to gradual involution (GI), whereas short-term or lack of breastfeeding leads to abrupt involution (AI) of the breast.
View Article and Find Full Text PDFCardiovasc Eng Technol
January 2025
Transonic Systems Inc., 34 Dutch Mill Road, Ithaca, New York, 14850, USA.
Purpose: Over time, transit time flow measurement (TTFM) has proven itself as a simple and effective tool for intra-operative evaluation of coronary artery bypass grafts (CABGs). However, metrics used to screen for possible technical error show considerable spread, preventing the definition of sharp cut-off values to distinguish between patent, questionable, and failed grafts. The simulation study presented in this paper aims to quantify this uncertainty for commonly used patency metrics, and to identify the most important physiological parameters influencing it.
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