In this paper, the behavior of precious metals and oil is examined using a fractionally integrated and cointegrated modeling approach. Using daily data from January 2015 to December 2020 and using both endogenous and exogenous structural breaks, we examine the behavior of the related series before and during the COVID-19 pandemic with the aim of investigating whether the degree of persistence has changed since the onset of COVID-19. We found that precious metals and oil exhibit long memory and are mean reverting regardless of the sample considered as the fractional parameter d < 0.5. However, when structural breaks are taken into consideration, an increase in persistence is found during the COVID-19 as compared to the period before it. In addition, the fractionally cointegrated vector autoregressive (FCVAR) model of Johansen and Nielsen (2010, 2012) is used to examine the existence of long-run relationship among precious metals and oil price. We find the integrated parameters at d < 0.5 for all samples except for the pre-COVID-19 sample. This highlights that the FCVAR is a better fit for the full sample and the COVID-19 and the COVID-19 pandemic period sub-samples, as the fractional parameter is d < 0.5 while the CVAR model is better fit for the pre-COVID-19 period where d> 0.5. Both cointegration techniques alongside the parameter stability tests lend support to the existence of a persistence and stable long-run relationships among the series irrespective of the sample period considered. Attendant policy recommendations for investors and policymakers are recommended.
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http://dx.doi.org/10.1007/s11356-021-15479-w | DOI Listing |
Angew Chem Int Ed Engl
January 2025
Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, Chemistry, Renmin Street, 130024, Changchun, CHINA.
High capacity, selective recovery and separation of precious metals from complex aqueous solutions is essential but remains a challenge in practical applications. Here, we prepared a thiophene-modified aromatic porous organic cage (T-PAC) with high stability for precise recognition and recovery of gold. T-PAC exhibits an outstanding gold uptake capacity of up to 2260 mg/g with fast adsorption kinetics and high adsorption selectivity.
View Article and Find Full Text PDFWorld J Microbiol Biotechnol
January 2025
Botany Department, Faculty of Science, Mansoura University, Mansoura, 35516, Egypt.
There is still much to be learned about the properties of siderophores and their applications. This study was designed to characterize and optimize the production of the siderophore produced by a marine bacterium Pseudomonas sp. strain ASA235 and then evaluate their use in bioleaching of rare earth elements (REEs) from spent Nickel-metal hydride (NiMH) batteries.
View Article and Find Full Text PDFSmall
January 2025
College of Chemistry, Fuzhou University, Fuzhou, 350116, P. R. China.
Metal-free molecular perovskites have shown great potential for X-ray detection due to their tunable chemical structures, low toxicity, and excellent photophysical properties. However, their limited X-ray absorption and environmental instability restrict their practical application. In this study, cesium-based molecular perovskites (MDABCO-CsX, X = Cl, Br, I) are developed by introducing Cs at the B-site to enhance X-ray absorption while retaining low toxicity.
View Article and Find Full Text PDFDalton Trans
January 2025
School of Materials Science and Engineering, China University of Petroleum, Qingdao, 266580, PR China.
Non-precious transition metal-based electrocatalysts with high activities are promising candidates for substituting Pt- or Ru-based electrocatalysts in hydrogen evolution. In this study, we propose core-shell engineering to combine the amorphous NiCoP and crystalline CoP (a-NiCoP/CoP@NF), which requires an ultra-low overpotential of only 26 mV to achieve the benchmark current density of 10 mA cm. Furthermore, it achieves an industrial-level hydrogen evolution current density of 500 mA cm with excellent stability.
View Article and Find Full Text PDFChem Commun (Camb)
January 2025
School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 401331, China.
Polymer electrolyte membrane fuel cells (PEMFCs) are one of the most promising energy conversion devices due to their high efficiency and zero emission; however, two major challenges, high cost and short lifetime, have been hindering the commercialization of fuel cells. Achieving low-Pt or non-precious metal oxygen reduction reaction (ORR) electrocatalysts is one of the main research ideas in this field. In this review, the degradation mechanism of Pt-based catalysts is firstly explained and elucidated, and then five strategies are suggested for the reduction of Pt usage without loss of activity and durability: modulation of metal-support interactions, optimization of local ionomers and mass transport, modulation of composition, modulation of structure, and multi-site synergistic effects.
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