We experimentally demonstrate the efficient generation of circularly polarized pulses tunable from the vacuum to deep ultraviolet (160-380 nm) through resonant dispersive wave emission from optical solitons in a gas-filled hollow capillary fiber. In the deep ultraviolet, we measure up to 13 µJ of pulse energy, and from numerical simulations, we estimate the shortest output pulse duration to be 8.5 fs. We also experimentally verify that simply scaling the pulse energy by 3/2 between linearly and circularly polarized pumping closely reproduces the soliton and dispersive wave dynamics. Based on previous results with linearly polarized self-compression and resonant dispersive wave emission, we expect our technique to be extended to produce circularly polarized few-fs pulses further into the vacuum ultraviolet, and few to sub-fs circularly polarized pulses in the near infrared.
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http://dx.doi.org/10.1364/OL.432228 | DOI Listing |
Phys Chem Chem Phys
January 2025
College of Mechanics and Engineering Science, Hohai University, Nanjing, 211100, China.
Driven by the pressing demand for integration and miniaturization within the terahertz (THz) spectrum, this research introduces an innovative approach to construct chiral structures using dichroism as the target function. This initiative aims to tackle the prevalent issues of single-functionality, narrow application scope, and intricate design in conventional metasurfaces. The proposed multifunctional tunable metasurface employs a graphene-metal hybrid structure to address the critical constraints found in existing designs.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
January 2025
State Key Laboratory of Green Pesticide, Central China Normal University, Wuhan 430079, PR China. Electronic address:
The construction of helical structures through self-assembly and the exploration of their formation mechanisms not only amplify chiroptical properties but also provide profound insights into the structures and functions of natural helices. In this study, we developed a chiral Au(I) system based on BINAP and alkynyl ligands. The modification of the length or number of alkyl chains at the terminal positions of the alkynyl ligands significantly impacted the self-assembly behavior of the complexes.
View Article and Find Full Text PDFChemistry
January 2025
Natinal Institute of Adavanced Industrial Science and Technology, Interdisciplinary Research Center for Catalytic Chemistry, Higashi 1-1-1, 305-8565, Tsukuba, JAPAN.
Unprecedented (2E,4E,6Z,8Z)-nona-2,4,6,8-tetraenoate derivatives highly substituted by aryl groups have been synthesized by the reaction of rhodium complexes having aryl-substituted hexa-1,3,5-trienyl ligands with acrylates. These compounds have potential axial chirality, and their enantiomers are isolable by the chiral HPLC technique. Although the racemization barrier of isolated enantiomers was not high, it was found that a cyclic dimer synthesized by head-to-tail transesterification of a modified analog has quite a stable axial chirality even at a high temperature.
View Article and Find Full Text PDFChemistry
January 2025
Beijing Normal University, College of Chemistry, Xiejiekou NO.19, 100875, Beijing, CHINA.
Optically pure monosubstituted [n]paracyclophanes are promising candidates for material synthesis, asymmetric catalysis, and drug discovery. Thus far, only a few catalytic asymmetric synthesis processes have been reported for assessing these stained atropisomers. In this study, we describe a highly enantioselective synthesis of monosubstituted [n]paracyclophanes by combining desymmetrization and kinetic resolution.
View Article and Find Full Text PDFJ Phys Chem Lett
January 2025
Laboratory of Advanced Optoelectronic Materials, Suzhou Key Laboratory of Novel Semiconductor-Optoelectronics Materials and Devices, State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China.
Circularly polarized luminescence (CPL) materials have drawn increasing attention for their potential applications in optical displays and chemo/biosensing. Nevertheless, the construction of circularly polarized room-temperature phosphorescence (CPRTP) materials is still a significant challenge. In this work, four liquid crystalline polymer network films with RTP properties have been fabricated via photopolymerization of cholesteric liquid-crystalline mixtures containing different amounts of commercially available dyes.
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