In high purity -doped selenide glass pumped by a 4.08 µm Fe:ZnSe laser, 5.1-5.5 µm laser oscillations were observed. This is the first evidence of laser action corresponding to the → transition of ions.
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Aerosol Assisted Chemical Vapour Deposition (AACVD) of Zinc dichalcogenoimidodiphosphinate Complexes for the Deposition of Zinc Selenide Thin Films.
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School of Chemistry and School of Materials, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK.
Dichalcogenoimidodiphosphinate complexes of zinc [Zn{(EPPr)N}], [E=Se,Se; S,Se] were synthesized through metathetical reactions from the dichalcogenoimidodiphosphinate ligands [(EE'PPrNH)] (E, E'=Se, Se; S, Se). These complexes were characterized and used as single-source precursors through Aerosol-Assisted Chemical Vapour Deposition (AACVD) for the deposition of cubic zinc selenide (ZnSe) films on glass substrates. The deposition temperature occurred at 500 and 525 °C, while the flow rates of the carrier gas was 160 and 240 standard cubic centimetre (sccm).
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Department of Chemistry, Missouri University of Science and Technology, Rolla, Missouri 65409, United States.
A series of quaternary selenides, NaGaSe ( = Mn, Fe, and mixed Zn/Fe), have been synthesized for the first time employing a high-temperature solid-state synthesis route through stochiometric or polychalcogenide flux reactions. Along with the selenides, a previously reported sulfide analogue, NaFeGaS, is also revisited with new findings. These compounds form an interpenetrated structure made up of a supertetrahedral unit.
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Center for Ultrafast Science and Technology, School of Physics and Astronomy, Shanghai Jiao Tong University, Shanghai, 200240, China.
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Department of Semiconductor Electronics, Lviv Polytechnic National University, 12 Bandera str., Lviv, 79013, Ukraine. Electronic address:
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