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Electrochemically Promoted Asymmetric Transfer Hydrogenation of 2,2,2-Trifluoroacetophenone. | LitMetric
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Electrochemically Promoted Asymmetric Transfer Hydrogenation of 2,2,2-Trifluoroacetophenone.

Huan Wang Ying-Na Yue Rui Xiong Yu-Ting Liu Li-Rong Yang Ying Wang Jia-Xing Lu

J Org Chem

Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China.

Published: November 2021

The study reported an electrochemically promoted asymmetric hydrogen transfer reaction of 2,2,2-trifluoroacetophenone with a chiral Ru complex. ()-α-(Trifluoromethyl) benzyl alcohol with a 96% yield and 94% ee could be obtained with only a 0.5 F mol charge amount at room temperature and normal pressure.

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 Source
http://dx.doi.org/10.1021/acs.joc.1c01030DOI Listing

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