The influence of kinetic hydrate inhibitors on the process of natural gas hydrate nucleation was studied using the method of dielectric spectroscopy. The processes of gas hydrate formation and decomposition were monitored using the temperature dependence of the real component of the dielectric constant ε'(T). Analysis of the relaxation times τ and activation energy ΔE of the dielectric relaxation process revealed the inhibitor was involved in hydrogen bonding and the disruption of the local structures of water molecules.
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http://dx.doi.org/10.3390/molecules26154459 | DOI Listing |
Polymers (Basel)
January 2025
Faculty of Science and Industrial Technology, Prince of Songkla University, Surat Thani Campus, Surat Thani 84000, Thailand.
This research examines the possibility of palm oil and oil palm trunk biochar (OPTB) from pyrolysis effectively serving as alternative processing oils and fillers, substituting petroleum-based counterparts in natural rubber (NR) composites. Chemical, elemental, surface and morphological analyses were used to characterize both carbon black (CB) and OPTB, by using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) gas porosimetry, and scanning electron microscopy (SEM). The influences of OPTB contents from 0 to 100 parts per hundred rubber (phr) on thermal, dielectric, dynamic mechanical, and cure characteristics, and the key mechanical properties of particulate NR-composites were investigated.
View Article and Find Full Text PDFSensors (Basel)
January 2025
Faculty of Physics, Warsaw University of Technology, Koszykowa 75, 00-662 Warsaw, Poland.
Terahertz radiation patterns can be registered using various detectors; however, in most cases, the scanning resolution is limited. Thus, we propose an alternative method for the detailed scanning of terahertz light field distributions after passing simple and complex structures. Our method relies on using a dielectric waveguide to achieve better sampling resolution.
View Article and Find Full Text PDFMolecules
January 2025
Chemistry Department, Faculty of Science, Cairo University, Giza 12613, Egypt.
In recent years, the anti-corrosive properties of natural extracts as environmentally friendly inhibitors have gained considerable interest. This study evaluates the potential of ( L.) essential oil (), collected from Salé, Morocco, as a corrosion inhibitor for mild steel in 1 M HCl medium.
View Article and Find Full Text PDFMaterials (Basel)
January 2025
China Building Materials Academy, Beijing 100024, China.
xTiO-(1-x)SiO (x = 2.9~8.2 mol%) glass specimens were synthesized using the flame hydrolysis technique.
View Article and Find Full Text PDFACS Nano
January 2025
Beijing Academy of Quantum Information Sciences, Beijing 100193, P. R. China.
The quantum-well-like two-dimensional lead-halide perovskites exhibit strongly confined excitons due to the quantum confinement and reduced dielectric screening effect, which feature intriguing excitonic effects. The ionic nature of the perovskite crystal and the "softness" of the lattice induce the complex lattice dynamics. There are still open questions about how the soft lattices decorate the nature of excitons in these hybrid materials.
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