The increased demand for high performance gas turbine engines has resulted in a continuous search for new base materials and coatings. With the significant developments in nickel-based superalloys, the quest for developments related to thermal barrier coating (TBC) systems is increasing rapidly and is considered a key area of research. Of key importance are the processing routes that can provide the required coating properties when applied on engine components with complex shapes, such as turbine vanes, blades, etc. Despite significant research and development in the coating systems, the scope of electrodeposition as a potential alternative to the conventional methods of producing bond coats has only been realised to a limited extent. Additionally, their effectiveness in prolonging the alloys' lifetime is not well understood. This review summarises the work on electrodeposition as a coating development method for application in high temperature alloys for gas turbine engines and discusses the progress in the coatings that combine electrodeposition and other processes to achieve desired bond coats. The overall aim of this review is to emphasise the role of electrodeposition as a potential cost-effective alternative to produce bond coats. Besides, the developments in the electrodeposition of aluminium from ionic liquids for potential applications in gas turbines and the nuclear sector, as well as cost considerations and future challenges, are reviewed with the crucial raw materials' current and future savings scenarios in mind.
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http://dx.doi.org/10.3390/ma14154214 | DOI Listing |
Small
November 2024
Interdisciplinary Research Center of Biology & Catalysis, School of Life Sciences, Northwestern Polytechnical University, 1 Dongxiang Road, Xi' an, 710129, China.
Single-atom catalysts (SACs) with nitrogen-coordinated active centers feature unique electronic and geometric structures and thus show high catalytic activity for various industrial reactions. Searching for operable synthesis protocols to accurately devise SACs is vital but remains challenging because commonly used high-temperature pyrolysis always causes unpredictable structural changes and inhomogeneous single-atom sites. Herein, a mild bond-plucking strategy is reported to construct atomically dispersed Cu supported on graphene-liked CN (g-CN) under lower than 100 °C, and Cu foam is used as the source of metal.
View Article and Find Full Text PDFVet Dermatol
February 2025
Department of Clinical Sciences and Services, Royal Veterinary College, Hatfield, Herts, UK.
Odontology
July 2024
Departament of Restorative Dentistry, Dental Materials Division, Piracicaba Dental School, Post-Graduation Program in Dental Materials, State University of Campinas, 901 Limeira Ave, Areião, Piracicaba, São Paulo, 13414-903, Brazil.
To evaluate the effect of adhesive coats application on the enamel microtensile bond strength (µTBS) of universal adhesives, morphological etching pattern and their chemical interaction with hydroxyapatite (HA). Two universal adhesives were investigated: Scotchbond Universal (SBU, 3 M) and Prime&Bond Universal (PBU, Dentsply). The adhesives were applied in self-etching mode on bovine enamel (n = 8) in one (1L), two (2L) or three coats (3L) and light-cured as per manufacturers' instructions.
View Article and Find Full Text PDFOdontology
June 2024
Post-Graduate Program in Oral Science, Faculty of Dentistry, Federal University of Santa Maria (UFSM), Roraima Avenue #1000, T Street, Building 26F, Room 2383, Santa Maria, Rio Grande do Sul, 97105-900, Brazil.
This study aimed to evaluate the influence of radiotherapy and different endodontic treatment protocols on the bond strength to pulp chamber dentin. Eighty mandibular molars were randomly divided into two groups (n = 40): non-irradiated and irradiated (60 Gy). The pulp chambers were sectioned, and each group was subdivided (n = 8), according to the endodontic treatment protocol: no treatment (Control); Single-visit; Two-visits; Immediate dentin sealing (IDS) + single-visit; and IDS + two-visits.
View Article and Find Full Text PDFClin Cosmet Investig Dent
May 2024
Department of Restorative Dentistry, Piracicaba Dental School, University of Campinas, Piracicaba, SP, Brazil.
Objective: This study aimed to evaluate the bond strength of a universal adhesive to dentin (μTBS) using different time periods of airborne particle abrasion (APA) and two types of acid etching.
Methods: Seventy-two human third molars were divided into 9 groups (n=8) according to dentin pretreatment: APA duration (0, 5, or 10s) and acid etching (no acid - NA, 37% phosphoric acid - PhoA, or 1% phytic acid - PhyA). APA was performed at a 0.
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