Application of dimensional analysis in sorption modeling of the styryl pyridinium cationic dyes on reusable iron based humic acid coated magnetic nanoparticles.

Cationic dyes exist in various industrial wastewaters and removal prior to discharge is necessary due to their carcinogenic behavior which poses a serious threat to human health. Iron based humic acid coated magnetic nanoparticles (HA-MNPs) were evaluated for the removal of 2-[4-(dimethylamino) styryl]-1-methylpyridinium iodide (2-ASP) as a model compound for cationic styryl pyridinium dyes from aqueous media. HA-MNPs were prepared by co-precipitation and characterized. The adsorption of 2-ASP, measured by fluorescence, demonstrates HA-MNPs are efficient for the 2-ASP removal with a maximum adsorption capacity of ~8 mg/g. Kinetic behavior and equilibrium studies showed the adsorption process fits with pseudo 2nd order and Langmuir isotherm models. The adsorption is relatively fast with ~70% of the adsorption complete within 30 min. The overall removal increases by increasing solution pH. The observed increase in adsorption can be assigned to an enhanced electrostatic attraction between the positively charged 2-ASP and the increase in the negative charge on the HA-MNPs surface as a function of increasing solution pH. Effective and repetitive regeneration of the HA-MNPs was achieved using NaOH treatment of saturated sorbent. Regeneration of HA-MNPs showed that removal efficiency remains consistently high after five consecutive cycles. Dimensional analysis suggested that initial concentration/sorbent dose ratio should be considered for accurate sorption modeling confirmed by experimental data. Then generalized empirical models for isothermal study and removal efficiency prediction were accurately deduced. This finding will help researchers in sorption studies to design their experiments more efficiently and to develop improved empirical models in removal prediction.