We develop a novel approach to suspend ice in the air-trapping Cassie state without requiring any fragile hydrophobic coatings or nanostructures. First, frost was preferentially grown on the tops of hydrophilic aluminum pillars due to their sharp corners and elevation over the noncondensable gas barrier. Subsequently, Cassie ice was formed by virtue of the impacting droplets getting arrested by the upper frost tips. A scaling model reveals that the dynamic pressure of an impacting droplet causes the water to wick inside the porous frost faster than the timescale to impale between the pillars.
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http://dx.doi.org/10.1103/PhysRevLett.127.044501 | DOI Listing |
Nat Commun
November 2024
Center of Resource Chemistry and Energy Materials, Key Laboratory of Clay Mineral of Gansu Province, and State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, PR China.
Photothermal superhydrophobic coatings are supposed promising to prevent ice accumulation on infrastructures but often experience significant performance degradation in real icing conditions and lack mechanical robustness. Here, we report design of robust photothermal superhydrophobic coatings with three-tier hierarchical micro-/nano-/nanostructures by deposition of nanosized MOFs on natural attapulgite nanorods, fluorination, controlled phase separation of a hydrophobic adhesive and spraying assembly. Phase separation degree and adhesive content significantly influence the coatings' properties by regulating the structural parameters and morphology.
View Article and Find Full Text PDFRSC Adv
October 2024
Lab for Micro Molding and Polymer Rheology, Guangdong Provincial Key Laboratory of Technique and Equipment for Macromolecular Advanced Manufacturing, South China University of Technology Guangzhou 510640 People's Republic of China
In this work, a superhydrophobic polypropylene (PP) replica with nanowires is fabricated using an injection compression molding (ICM) process. The morphology, superhydrophobicity and fog water harvesting efficiency of the as-prepared PP replica surface are investigated. Morphological characterization indicates that the PP replica surface exhibits nanowires with intertwined tips.
View Article and Find Full Text PDFAdv Mater
July 2024
State Key Laboratory of Optoelectronic Materials and Technologies, School of Materials Science and Engineering, Sun Yat-sen University, Guangzhou, 510006, China.
J Colloid Interface Sci
September 2024
Department of Applied Sciences, University of Québec in Chicoutimi, Chicoutimi, Québec, Canada.
Hypothesis: Superhydrophobic surfaces can effectively prevent the freezing of supercooled droplets in technological systems. Droplets on superhydrophobic surfaces commonly not only wet the top asperities (Cassie State), but also partially penetrate into microstructure due to surface properties, environment, and droplet impact occurring in real-world applications. Implications on ice nucleation can be expected and are little explored.
View Article and Find Full Text PDFACS Nano
May 2024
Laser Materials Processing Research Center, Key Laboratory for Advanced Materials Processing Technology (Ministry of Education), Joint Research Center for Advanced Materials & Anti-icing of Tsinghua University (SMSE)-AVIC ARI, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, P. R. China.
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