Understanding the impact of doping variations on the physical properties of two-dimensional materials is important for their application in electronic and optoelectronic devices. Here we report a nano-optical study on graphene and MoS homojunctions by placing these two materials partly on top of a layered talc substrate, partly on top of an SiO substrate. By analyzing the nano-Raman scattering from graphene and the nanophotoluminescense emission from MoS, two different doping zones are evident with sub-100 nm wide charge oscillations. The oscillations occur abruptly at the homojuction and extend over longer distances away from the interface, indicating imperfect deposition of the two-dimensional layer on the substrate. These results evidence fine and unexpected details of the homojuctions, important to build better electronic and optoelectronic devices.
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http://dx.doi.org/10.1021/acs.jpclett.1c01804 | DOI Listing |
J Colloid Interface Sci
January 2025
School of Materials Science and Engineering, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240 China.
As a graphene-like layered material, molybdenum disulfide (MoS), has attracted increasing attentions for its promising application in electrocatalysis. Whereas MoS still suffers from the sluggish reaction kinetics in oxygen evolution reaction (OER) due to the low density of active sites in most exposed planes. In this work, high density of active sites on MoS basal planes has been obtained by synthesizing mesoporous MoS with Co doping and sulfur vacancies (V).
View Article and Find Full Text PDFJ Phys Chem Lett
January 2025
Key Laboratory of Materials Physics, Institute of Solid State Physics, HFIPS, Chinese Academy of Sciences, Hefei 230031, China.
Unveiling the nonlinear interactions between terahertz (THz) electromagnetic waves and free carriers in two-dimensional materials is crucial for the development of high-field and high-frequency electronic devices. Herein, we investigate THz nonlinear transport dynamics in a monolayer graphene/MoS heterostructure using time-resolved THz spectroscopy with intense THz pulses as the probe. Following ultrafast photoexcitation, the interfacial charge transfer establishes a nonequilibrium carrier redistribution, leaving free holes in the graphene and trapping electrons in the MoS.
View Article and Find Full Text PDFJ Hazard Mater
December 2024
School of Environmental Science and Engineering, Southern University of Science and Technology, Shenzhen 518055, China; Guangdong Provincial Key Laboratory of Soil and Groundwater Pollution Control, School of Environmental Science and Engineering, Southern University of Science and Technology, Shenzhen 518055, China. Electronic address:
Understanding the behavior and fate of microplastics (MPs) in aquatic environment is crucial for assessing their potential risks. This study investigated the heteroaggregation behaviors of MPs with representative 2D nanosheets, MoS and graphene oxide (GO), under various conditions, focusing on the transport behavior of the resulting aggregates. It was found that the destabilization capabilities of 2D nanosheets are notably stronger than those of well-reported nanoparticles.
View Article and Find Full Text PDFAdv Mater
January 2025
Institute for Superconducting & Electronic Materials (ISEM), Faculty of Engineering and Information Sciences, University of Wollongong, Innovation Campus, Squires Way, North Wollongong, NSW, 2500, Australia.
Chem Asian J
January 2025
Energy Materials Laboratory, Centre for Nano and Soft Matter Sciences, Bangalore, 562162, India.
The widespread demand for battery-powered technologies has propelled the search for efficient and commercially viable electrode materials with fast-charging abilities. Reported herein is an MoS-expanded graphite (EG) composite as a stable and high-rate lithium-ion battery (LIB) anode, delivering specific capacities of 796 mAh g at 0.5 A g and 320 mAh g at 20 A g over 400 cycles.
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