The single-crystal spectropolarimeter envisioned by Baronova and Stepanenko splits an incident x-ray beam into two beams with mutually orthogonal linear polarizations by using simultaneous reflections at the perfectly polarizing 45° Bragg angle on certain pairs of internal planes in hexagonal or cubic crystals. These planes intersect along a threefold symmetry axis, making a 120° angle with each other, and are typically symmetric with respect to the crystal surface. In practice, the wavelength of the diagnostic x-ray lines does not exactly satisfy Bragg's law for the crystal in the ideal polarizing orientation, so the extinction of reflections is incomplete. Accepting this limitation, this paper shows that for cubic crystals, other pairs of internal planes exist that satisfy the polarization requirements approximately. Typically, they are accessible from the perfect polarization-splitting geometry by small rotations of the crystal. This paper includes examples of such planes for cubic crystals with {110} and {211} surface cuts.
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http://dx.doi.org/10.1063/5.0047035 | DOI Listing |
Sci Rep
January 2025
Center for Advanced Materials and Structures, School of Science and Technology, The University of Georgia, 0171, Tbilisi, Georgia.
In this work, cerium dioxide nanostructures were synthesized in an easy sonochemical way. CeO nanoparticles have received much attention in nanotechnology. CeONPs, exhibit biomimetic properties depending on their size, ratio of valency on their surface, and the ambient physico-chemical properties.
View Article and Find Full Text PDFACS Nano
January 2025
Faculty III Process Sciences, Institute of Materials Science and Technology, Chair of Advanced Ceramic Materials, Technische Universität Berlin, Straße des 17. Juni 135, 10623 Berlin, Germany.
Metastable, , kinetically favored but thermodynamically not stable, interstitial solid solutions of carbon in iron are well-understood. Carbon can occupy the interstitial atoms of the host metal, altering its properties. Alloying of the host metal results in the stabilization of the FeC phases, widening its application.
View Article and Find Full Text PDFJ Chem Phys
January 2025
Department of Chemistry, Indian Institute of Science Education and Research (IISER) Tirupati, Tirupati, Andhra Pradesh 517619, India.
Although impurities are unavoidable in real-world and experimental systems, most numerical studies on nucleation focus on pure (impurity-free) systems. As a result, the role of impurities in phase transitions remains poorly understood, especially for systems with complex free energy landscapes featuring one or more intermediate metastable phases. In this study, we employed Monte Carlo simulations to investigate the effects of static impurities (quenched disorder) of varying length scales and surface morphologies on the crystal nucleation mechanism and kinetics in the Gaussian core model system-a representative model for soft colloidal systems.
View Article and Find Full Text PDFJ Phys Condens Matter
January 2025
Nanjing University, Hankou Road 22, School of Physics, Nanjing University, Nanjing, Jiangsu, 210093, CHINA.
Driven by the miniaturization of microelectronic devices and their multifunctionalities, the development of new quadruple-perovskite oxides with high dielectric constants and high Curie temperature are highly required. Herein, we report on the structural, dielectric and magnetic properties of Sb/Cr-doped CaCu3Ti4O12 (CCTO) quadruple perovskite oxides, CaCu3Ti3.9Sb0.
View Article and Find Full Text PDFAdv Mater
January 2025
Felix-Bloch-Institut für Festkörperphysik, Universität Leipzig, Linnéstraße 5, 04103, Leipzig, Germany.
Stable Sb exhibits a rhombohedral structure, often referred to as distorted primitive cubic, with each Sb atom having three short and three longer first neighbor bonds. However, this crystal structure can also be interpreted as being layered, putting emphasis on only three short first neighbor bonds. Therefore, temperature-dependent extended X-ray absorption fine structure (EXAFS) spectroscopy is carried out at the Sb K-edge in order to obtain more detailed information on local structural and vibrational properties.
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