Electrochemiluminescence of water-dispersed nitrogen and sulfur doped carbon dots synthesized from amino acids.

A facile one-pot hydrothermal approach for synthesizing water-dispersed nitrogen and sulfur doped carbon dots (NS-CDs) with high luminescence quantum yield was explored, using cysteine and tryptophan as precursors. The NS-CDs were characterized by means of FT-IR spectroscopy, XRD, TEM, etc. It was found that the absolute photoluminescence quantum yield (QY) of the NS-CDs determined with an integrating sphere can reach up to 73%, with an average decay time of 17.06 ns. Electrochemiluminescence (ECL) behaviors and mechanisms of the NS-CDs/KSO coreactant system were investigated. When the working electrode was modified with the prepared NS-CDs, the ECL efficiency of the NS-CDs with KSO was 24%, relative to Ru(bpy)Cl/KSO. This work shows great potential for the NS-CDs to be used in bioanalytical applications.