MnMnNbO: high-pressure triple perovskite with 1 : 2 B-site order and modulated spins.

Chem Commun (Camb)

Univ. Lille, CNRS, Centrale Lille, ENSCL, Univ. Artois, UMR 8181-UCCS-Unité de Catalyse et Chimie du Solide, Lille F-59000, France.

Published: September 2021

The first triple perovskite with Mn in A- and 1 : 2 B-site order MnMnNbO, prepared using high pressure phase transformation of the magnetodielectric MnNbO, is reported herein. It has a complex magnetic behaviour with a transition from a collinear AFM into an evolving incommensurate spin density wave (SDW) further stabilised into a lock-in structure dictated by the B-site order.

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http://dx.doi.org/10.1039/d1cc02782dDOI Listing

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