A dual-functional layer modified GO@SiO membrane with excellent anti-fouling performance for continuous separation of oil-in-water emulsion.

As the most significant target of membrane separation, the inadequacy of permeability and anti-fouling frequently constrain the application of the membrane in actual oily wastewater. Herein, a novel concept of membrane surface construction was proposed to mitigate this intractable problem, using SiO as the support layer and graphene oxide (GO) as the isolation layer. The best co-localization proportion of the support layer (56 mg/L) and isolation layer (3.5 mg/L) was determined by the separation performance of the modified membranes for the simulated emulsion. The thin GO layer could effectively prevent contaminants from entering the membrane pores without affecting its roughness. Based on the synergistic action of the isolation layer and support layer, the GO@SiO membrane could well implement emulsion purification with a stable permeability (654.11 LMHB) and high separation efficiency (99.41%). The superior anti-fouling performance of the membrane ensures its long-term cycling stability, with the permeability recovery rate of 89.75% (low-density oil) and 90.41% (high-density oil) after 10 repeated cycles. The storage stability also indirectly increases its value in practical applications. More importantly, the GO@SiO membrane also shows great potential for industrial emulsion treatment with excellent purification and cycling stability (permeability recovery rate of 84.01%).