Migration of leather tannins and chromium in soils under the effect of simulated rain.

Chromium (Cr) and tannin are two major pollutants in leather industry. However, little is known about the co-migration of leather tannins and Cr in soils. In this study, column experiments were conducted to estimate Cr leaching behavior from topsoil and the environmental risk of the leachate at various tannin dosages and different ways (tannin either directly adding to the Cr-contaminated soil or adding stepwise through simulated rain) into the soil. The total Cr concentration in leachate was positively related with tannin content in soil, while Cr (Ⅵ) concentration was negatively correlated. The maximum cumulative leaching efficiency of total Cr from soil after six leaching events was 44.65% with 3 mg/g tannin adding into soil directly, and the maximum cumulative leaching efficiency of Cr (Ⅵ) was 38.75% with simulated rain leaching Cr-contaminated soil. With 3 mg/g tannin adding into soil, tannin concentration in the top layer (0-7 cm) lost by 32.67% after leaching, the amount of decomposed tannin was 0.25 mg/g, excluding the amount of tannin in leachate (3.63 mg/L) and the original amount in the soil (0.34 mg/g), indicating a slow degradation under natural condition. Both of the total Cr and Cr (Ⅵ) concentration in each layer of the soil columns decreased under tannin treatments compared with control. Compared with tannin adding stepwise into simulated rain, adding tannin into soil significantly (p < 0.05) affected the migration of Cr. Tannin increased the residual fraction while decreased the exchangeable fraction of Cr in the soils. Overall, this research can provide reference information for environmental risk assessment of contaminants in tanning sites.