In order to treat the high concentration landfill leachate, ozone direct oxidation pretreatment and catalytic oxidation post-treatment coupled with anaerobic baffled membrane bioreactor (ABMBR) system was proposed in this study. For pretreatment, ozone direct oxidation could remarkably reduce UV, 3D fluorescence peak value and fluorescence regional integration (FRI) of organic pollutants. For ABMBR treatment, the removal efficiencies of COD and ammonia nitrogen were 80.38% and 21.56%, respectively. Post-treatment included struvite precipitation, ozone catalytic oxidation and membrane bioreactor (MBR) treatment. Finally, the total removal efficiencies of COD and ammonia nitrogen were 91.2% and 99.4%, respectively. The chroma was remarkably decreased from 1250 times to 40 times after a series of treatments. The acids in ABMBR could be degraded by microorganisms of Proteobacteria and Chloroflexi. The cellulose and polysaccharides could be decomposed by Bacteroidetes and ketones could be decomposed by Brevundimonas in ABMBR. Electron paramagnetic resonance (EPR) analysis indicated that the hydroxyl radicals were the main reactive oxygen species during the direct ozone oxidation process, while the superoxide radicals played an important role in the ozone catalytic oxidation process.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1016/j.scitotenv.2021.148557 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Ultrasonically Activated Liquid Metal Catalysts in Water for Enhanced Hydrogenation Efficiency.
ACS Appl Mater Interfaces
January 2025
Department of Chemistry and Materials Engineering, Kansai University, 3-3-35 Yamate-cho, Suita, Osaka 564-8680, Japan.
Hydride (H) species on oxides have been extensively studied over the past few decades because of their critical role in various catalytic processes. Their syntheses require high temperatures and the presence of hydrogen, which involves complex equipment, high energy costs, and strict safety protocols. Hydride species tend to decompose in the presence of atmospheric oxygen and water, which reduces their catalytic activities.
View Article and Find Full Text PDFCrystal structure and functional characterization of a novel bacterial lignin-degrading dye-decolorizing peroxidase.
Int J Biol Macromol
January 2025
Department of Life Sciences and Systems Biology, University of Torino, Italy.
A new gene coding for an iron-containing enzyme was identified in the genome of Acinetobacter radioresistens. Bioinformatics analysis allowed the assignment of the protein to DyP peroxidases, due to the presence of conserved residues involved in heme binding and catalysis. Moreover, Ar-DyP is located in an operon coding also for other enzymes involved in iron uptake and regulation.
View Article and Find Full Text PDFHierarchical Selenium-Doped Nickel-Cobalt Hybrids on Carbon Paper for the Overall Water-Splitting Electrocatalytic System.
ACS Appl Mater Interfaces
January 2025
Department of Battery and Chemical Engineering, Hanyang University, Ansan, Gyeonggi-do 15588, Republic of Korea.
Designing and constructing hierarchically structured materials with heterogeneous compositions is the key to developing an effective catalyst for overall water-splitting applications. Herein, we report the fabrication of hollow-structured selenium-doped nickel-cobalt hybrids on carbon paper as a self-supported electrode (denoted as Se-Ni|Co/CP, where Ni|Co hybrids consist of nickel-cobalt alloy-incorporated nickel-cobalt oxide). The procedure involves direct growth of zeolitic imidazolate framework-67 (ZIF-67) on bimetal-based nickel-cobalt hydroxide (NiCoOH) electrodeposited on CP, followed by selenous etching and pyrolysis to obtain the final Se-Ni|Co/CP electrocatalytic system.
View Article and Find Full Text PDFCu@DPP-SPION: A Novel and Versatile Catalyst for the Synthesis of Thioxo-Tetrahydropyrimidine Derivatives under Mild Reaction Conditions.
Curr Org Synth
January 2025
Stem Cells Technology Research Center, Shiraz University of Medical Sciences, Shiraz, Iran.
Introduction: The development of efficient and sustainable catalytic methodolo-gies has garnered considerable attention in contemporary organic synthesis.
Methods: Herein, we present a novel approach employing the Cu@DPP-SPION catalyst for the synthesis of ethyl 4-(aryl)-6-methyl-2-thioxo-1,2,3,4-tetrahydropyrimidine-5-carboxylate derivatives. This versatile catalytic system incorporates copper nanoparticles supported on 4-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)benzoic acid-functionalized superparamagnetic iron oxide nanoparticles (SPIONs).
Green Synthesis of ZnO Nanoparticles Using Ficus benghalensis for Visible Light-Driven Photocatalytic Degradation of Crystal Violet and Antibacterial and Antibiofilm Activities.
Luminescence
January 2025
School of Chemical Engineering, Yeungnam University, Gyeongsan, Republic of Korea.
Crystal Violet (CV) is a vibrant and harmful dye known for its toxicity to aquatic life and potential carcinogenic effects on humans. This study explores the removal of CV through photocatalysis driven by visible light, as well as examining the antibacterial and antibiofilm characteristics of zinc oxide nanoparticles (ZnO NPs) synthesized from the aerial roots of Ficus benghalensis. Various characterization techniques were employed to confirm the optical properties, crystal lattices, and morphology of ZnO NPs.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!