Understanding the evolution of the nuclear charge radius is one of the long-standing challenges for nuclear theory. Recently, density functional theory calculations utilizing Fayans functionals have successfully reproduced the charge radii of a variety of exotic isotopes. However, difficulties in the isotope production have hindered testing these models in the immediate region of the nuclear chart below the heaviest self-conjugate doubly-magic nucleus Sn, where the near-equal number of protons (Z) and neutrons (N) lead to enhanced neutron-proton pairing. Here, we present an optical excursion into this region by crossing the N = 50 magic neutron number in the silver isotopic chain with the measurement of the charge radius of Ag (N = 49). The results provide a challenge for nuclear theory: calculations are unable to reproduce the pronounced discontinuity in the charge radii as one moves below N = 50. The technical advancements in this work open the N = Z region below Sn for further optical studies, which will lead to more comprehensive input for nuclear theory development.
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http://dx.doi.org/10.1038/s41467-021-24888-x | DOI Listing |
Inorg Chem
January 2025
State Key Laboratory of Nuclear Resources and Environment, East China University of Technology, Nanchang, Jiangxi 330013, China.
Extracting uranium from nuclear wastewater is vital for environmental and human health protection. However, despite progress in uranium extraction, there remains a demand for an optimized adsorbent with improved capability, efficiency, and selectivity. To bridge this gap, 1,2,3,4-butane tetracarboxylic acid (BTCA)-modified MIL-101 was synthesized through a simple hydrothermal reaction between amino-modified MIL-101 (MIL-101-NH) and BTCA.
View Article and Find Full Text PDFSmall
January 2025
Department of Botany and Microbiology, College of Science, King Saud University, P.O. Box 2455, Riyadh, 11451, Saudi Arabia.
A polyacrylamide gel method has been used to synthesize a variety of polyvalent-transition-metal-doped Ni position of high entropy spinel oxides (NiZnMgCuCo)AlO-800 °C (A) on the basis of NiAlO, and the catalytic activity of A is studied under the synergistic action of peroxymonosulfate (PMS) activation and simulated sunlight. The A containing polyvalent transition metals (Ni, Cu, and Co) can effectively activate PMS and efficiently degrade levofloxacin (LEV) and tetracycline hydrochloride (TCH) under simulated sunlight irradiation. After 90 min of light exposure, the degradation percentages of LEV (50 mg L) and TCH (100 mg L) degrade by the A/PMS/vis system reach 87.
View Article and Find Full Text PDFNat Commun
January 2025
Institute of Molecular Medicine (IMM), Renji Hospital, School of Medicine, Shanghai Jiao Tong University, Shanghai, China.
Multiple receptor analysis-based DNA molecular computation has been developed to mitigate the off-target effect caused by nonspecific expression of cell membrane receptors. However, it is quite difficult to involve nanobodies into molecular computation with programmed recognition order because of the "always-on" response mode and the inconvenient molecular programming. Here we propose a spatial segregation-based molecular computing strategy with a shielded internal computing layer termed DNA nano-phage (DNP) to program nanobody into DNA molecular computation and build a series of kinetic models to elucidate the mechanism of microenvironment-confinement.
View Article and Find Full Text PDFJ Colloid Interface Sci
January 2025
College of Chemistry and Materials Engineering, Zhejiang A&F University, No. 666 Wusu Street, Hangzhou 311300 PR China. Electronic address:
Developing biomass-based adsorbents with superior uranium uptake performance is imperative yet challenging for the sustainable development of nuclear energy. Herein, we constructed a novel lignin-based adsorbent (DLP@PAO) with dual functional groups and enhanced structural stability via ingenious integration of lignin and polyamidoxime. The two-step modification strategy was innovatively employed to phosphorylate lignin, significantly enhancing the phosphorylation efficiency and achieving an over eight-fold increase in the U(VI) uptake capacity of lignin.
View Article and Find Full Text PDFJ Hazard Mater
January 2025
Laboratory of Nuclear Energy Chemistry, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China; School of Nuclear Science and Engineering, and Key Laboratory of Nuclear Power Systems and Equipment/Ministry of Education, Shanghai Jiao Tong University, Shanghai 200240, China. Electronic address:
In this work, we use a well-defined water-soluble macrocyclic molecule cucurbit[5]uril (CB5) to modify 2D TiCT MXene and assemble a novel high-performance adsorbent CB5-TiCT for Sr ion by density functional theory and experimental methods. The structural stabilities of two distinct types of CB5-TiCT (T = F, O and OH) complexes, i.e.
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