Advances and challenges in the high-pressure rheology of complex fluids.

Complex fluids and soft materials are ubiquitous in nature and industry. In industrial processes, these materials often get exposed to high hydrostatic pressures. Some examples include polymer melts, crude oils, gas hydrates, food systems, foams, motor oils, lubricants, etc. In spite of the relevance and utilization of hydrostatic pressure in many industrial applications, the role of pressure on the rheological properties has not been examined extensively in the literature. We review the high-pressure rheometric systems and present advantages and drawbacks of various kinds of rheometers such as capillary rheometer, sliding plate rheometer, falling ball viscometer, and rotational rheometer. By outlining the design complexities, precision, low-torque resolution limits and the inherent error sources of each type are critically evaluated. Furthermore, the high-pressure rheology data, chosen to cover a broad range of pressures and material class ranging from simple Newtonian fluids (incompressible), complex non-Newtonian fluids and compressible fluids featuring various key applications from different industries, are reviewed. The literature suggests, while effect of pressure on the rheological behavior is vital for many applications, compared to the effects of temperature on the rheological behavior, knowledge of the effect of pressure is still in its infancy.