AI Article Synopsis
- The study introduces a new way to generate nitroxyl (HNO) without using liquids or harsh conditions, by reacting a gas with a solid donor.
- This method is quick and cost-effective, allowing for the production of gaseous HNO.
- The detection of HNO was achieved through both indirect methods, like measuring nitrous oxide with infrared spectroscopy, and direct methods using mass spectrometry and an electrochemical sensor.
Article Abstract
We present a novel nitroxyl (HNO) generation method, which avoids the need of using a liquid system or extreme experimental conditions. This method consists of the reaction between a gaseous base and an HNO donor (Piloty's acid) in the solid phase, allowing the formation of gaseous HNO in a fast and economical way. Detection of HNO was carried out indirectly, measuring the nitrous oxide (NO) byproduct of HNO dimerization using infrared spectroscopy, and directly, using mass spectrometry techniques and an electrochemical HNO sensor.
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| http://dx.doi.org/10.1016/j.jinorgbio.2021.111535 | DOI Listing |
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