The presence of polyfunctional ligands on the bio-macromolecules acts as an efficient adsorbent for heavy metal ions. Starch is one of the most abundant, easily available and cheap biopolymer of plant origin. However, native starch exhibits significantly low adsorption capacity due to the absence of some essential functional groups like carboxyl, amino or ester groups and is thus modified using various reaction routes like grafting, cross-linking, esterification, oxidation and irradiation for addition of functional groups to increase its adsorption capacity. The present review provides a comprehensive discussion on the above mentioned modification schemes of starch over the last 10-15 years highlighting their preparation methods, physico-chemical characteristics along with their adsorption capacities and mechanisms of heavy metal ions from water.
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