The Ti-Ca heterometallic MOF MUV-10 exhibits good dispersibility in phosphate buffer and low phosphate-induced degradation in comparison to other MOF systems. It induces no cytotoxicity towards cells of the immune system and no inmune response, making it an attractive candidate for biomedical applications and demonstrating its safe use for other applications.
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http://dx.doi.org/10.1039/d1tb00981h | DOI Listing |
Inorg Chem
January 2025
Department of Chemistry, Faculty of Basic Sciences, University of Maragheh, P.O. Box 55181-83111 Maragheh, Iran.
Global clean energy demands can be effectively addressed using the promising approach of hydrogen energy generation combined with less energy consumption. Hydrogen can be generated, and urea-rich wastewater pollution can be mitigated in a low-energy manner using the urea oxidation reaction (UOR). This paper seeks to assemble a unique electrocatalyst of a pristine 2D MOF, [Co(HBTC)(DMF)] (Co-MUM-3), from 1,3,5-benzenetricarboxylate (BTC) to oxidize urea in simulated seawater.
View Article and Find Full Text PDFInorg Chem
December 2024
The Institute for Advanced Studies (IAS), Wuhan University, Wuhan 430072, P. R. China.
There has long been a pursuit for a metal-organic framework (MOF)-based adsorbent for various hydrocarbon separations. Herein, we utilized simple trimesic acid and 1,2,4-triazole, together with the heterometallic strategy to produce two quaternary MOFs with a kgm-type structure. The cooperative coordination allows the immobilization of metal clusters into the pore channels, creating an appropriate pore size and high density of open metal sites.
View Article and Find Full Text PDFAdv Mater
November 2024
Sandia National Laboratories, 1515 Eubank Blvd. SE, Albuquerque, NM, 87123, USA.
High-entropy materials (HEMs) emerged as promising candidates for a diverse array of chemical transformations, including CO utilization. However, traditional HEMs catalysts are nonporous, limiting their activity to surface sites. Designing HEMs with intrinsic porosity can open the door toward enhanced reactivity while maintaining the many benefits of high configurational entropy.
View Article and Find Full Text PDFAdv Mater
October 2024
Department of Chemistry, University of California, Riverside, California, 92521, United States.
Isoreticular chemistry, which enables property optimization by changing compositions without changing topology, is a powerful synthetic strategy. One of the biggest challenges facing isoreticular chemistry is to extend it to ligands with strongly coordinating substituent groups such as unbound -COOH, because competitive interactions between such groups and metal ions can derail isoreticular chemistry. It is even more challenging to have an isoreticular series of carboxyl-functionalized MOFs capable of encompassing chemically disparate metal ions.
View Article and Find Full Text PDFAnal Chim Acta
August 2024
Key Laboratory of Interfacial Reaction & Sensing Analysis in Universities of Shandong, School of Chemistry and Chemical Engineering, University of Jinan, Jinan, 250022, PR China. Electronic address:
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