Rolling liquid droplets are of great interest for various applications including self-cleaning of surfaces. Interfacial resistance, in terms of pinning and shear rate, has a critical role in droplet rolling dynamics on hydrophobic surfaces. Lowering the interfacial resistance requires reducing the droplet wetting length and droplet fluid contact area on hydrophobic surfaces. The present study examines droplet rolling behavior on inclined hydrophobized metallic meshes, which facilitate reduced wetting length and contact area of droplets. Experiments are carried out using a high-speed recording facility to evaluate droplet translational and rolling velocities over various sizes of hydrophobized meshes. The flow field inside the droplet fluid is simulated in 3-dimensional space mimicking the conditions of experiments. The findings reveal that droplet translational velocity attains significantly higher values for hydrophobized meshes than plain hydrophobized metallic surfaces. Increasing the mesh size enhances the droplet velocity and reduces the droplet kinetic energy dissipation created by interfacial surface tension and shear forces. Increasing the droplet volume enhances the droplet velocity despite the fact that pinning and frictional forces increase at the liquid-mesh interface. Hence, for rolling droplets on the mesh surface, the increase in the gravitational force component becomes larger than the increase in interfacial pinning and frictional forces.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1039/d1sm00746g | DOI Listing |
RSC Adv
January 2025
The Center for Chemical Biology, School of Fundamental Science and Technology, Graduate School of Science and Technology, Keio University 3-14-1 Hiyoshi, Kohoku-ku Yokohama 223-8522 Japan +81-45-566-1580 +81-45-566-1839.
We prepared a cellulose nanofiber (CNF)-based porous membrane with three dimensional cellular structures. CNF was concentrated a surfactant-induced assembly by mixing CNF with a cationic surfactant, domiphen bromide (DB). Furthermore, they were accumulated by centrifugation to obtain a CNF-DB sol.
View Article and Find Full Text PDFACS Appl Bio Mater
January 2025
Department of Chemistry, National Institute of Technology, Rourkela, Odisha 769008, India.
The idea of coordinating biologically active ligand systems to metal centers to exploit their synergistic effects has gained momentum. Therefore, in this report, three Ru complexes - of morpholine-derived thiosemicarbazone ligands have been prepared and characterized by spectroscopy and HRMS along with the structure of through a single-crystal X-ray diffraction study. The solution stability of - was tested using conventional techniques such as UV-vis and HRMS.
View Article and Find Full Text PDFWater Environ Res
January 2025
Zhejiang Key Laboratory of Petrochemical Environmental Pollution Control, Zhejiang Ocean University, Zhoushan, P. R. China.
The discharge of oil-laden wastewater from industrial processes and the frequent occurrence of oil spills pose severe threats to the ecological environment and human health. Membrane materials with special wettability have garnered attention for their ability to achieve efficient oil-water separation by leveraging the differences in wettability at the oil-water interface. These materials are characterized by their simplicity, energy efficiency, environmental friendliness, and reusability.
View Article and Find Full Text PDFFood Chem
January 2025
Department of Molecular Biology and Genetics, Faculty of Science, Ataturk University, 25240, Erzurum, Turkey. Electronic address:
Recycling of protein-rich environmental wastes and obtaining more valuable products from these recycled products is a topic of interest for researchers. This study aims to produce, purify, and characterize the physicochemical and structural properties of the protease enzyme produced from Brevibacillus agri SAR25 using salmon fish waste as substrate and also to evaluate the effect of protease on the chicken feather, enzyme-ligand interactions, and active site surface area. The production of protease was optimum on 50 g/L fish waste, pH 8, 40 °C, 96 h, and 150 rpm.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
University of Fribourg Faculty of Science: Universite de Fribourg Faculte de sciences et de medecine, Adolphe Merkle Institue, Chemin des Verdiers 4, 1700, Fribourg, SWITZERLAND.
Metal halide perovskites have shown exceptional potential in converting solar energy to electric power in photovoltaics, yet their application is hampered by limited operational stability. This stimulated the development of hybrid layered (two-dimensional, 2D) halide perovskites based on hydrophobic organic spacers, templating perovskite slabs, as a more stable alternative. However, conventional organic spacer cations are electronically insulating, resulting in charge confinement within the inorganic slabs, thus limiting their functionality.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!