In recent years, layered double hydroxide-biochar (LDH-BC) composites as adsorbents and catalysts for contaminants removal (inorganic anions, heavy metals, and organics) have received increasing attention and became a new research point. It is because of the good chemical stability, abundant surface functional groups, excellent anion exchange ability, and good electronic properties of LDH-BC composites. Hence, we offer an overall review on the developments and processes in the synthesis of LDH-BC composites as adsorbents and catalysts. Special attention is devoted to the strategies for enhancing the properties of LDH-BC composites, including (1) magnetic treatment, (2) acid treatment, (3) alkali treatment, (4) controlling metal ion ratios, (5) LDHs intercalation, and (6) calcination. In addition, further studies are called for LDH-BC composites and potential areas for future application of LDH-BC composites are also proposed.
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http://dx.doi.org/10.1016/j.jhazmat.2021.126569 | DOI Listing |
Materials (Basel)
June 2024
School of Environment and Energy, South China University of Technology, Guangzhou 510006, China.
Compound contamination of soil with heavy metals copper (Cu) and lead (Pb) triggered by mining development has become a serious problem. To solve this problem, in this paper, corncob kernel, which is widely available and inexpensive, was used as the raw material of biochar and modified by loading CaAl-layered double hydroxides to synthesize biochar-loaded CaAl-layered double hydroxide composites (CaAl-LDH/BC). After soil remediation experiments, either BC or CaAl-LDH/BC can increase soil pH, and the available phosphorus content and available potassium content in soil.
View Article and Find Full Text PDFChemosphere
May 2023
Zhejiang Province Key Laboratory of Recycling and Ecological Treatment of Waste Biomass, School of Environment and Natural Resources, Zhejiang University of Science and Technology, 318 Liuhe Road, Xihu District, Hangzhou, Zhejiang, 310023, China. Electronic address:
Layered double hydroxide-biochar composites (LDH@BCs) have been developed for ammonia nitrogen (AN) and phosphorus (P) removal from wastewater. Improvement of LDH@BCs was limited due to the lack of comparative evaluation based on LDH@BCs characteristics and synthetic methods and information on the adsorption properties of LDH@BCs for N and P from natural wastewater. In this study, MgFe-LDH@BCs were synthesized by three different co-precipitation procedures.
View Article and Find Full Text PDFChemosphere
December 2022
Department of Agricultural and Biological Engineering, University of Florida, Gainesville, FL, 32611, United States. Electronic address:
Improving the adsorption ability of layered double hydroxide (LDH) has been considered as a promising strategy to promote its photodegradation of aqueous pollutants. In this work, nickel-aluminium layered double hydroxides (NiAl-LDH)/biochar nanocomposites were prepared using a simple coprecipitation method, and then applied in synergistic adsorption-photodegradation of tetracycline (TC) in aqueous solutions. In addition, the governing TC removal mechanisms by the nanocomposites were revealed.
View Article and Find Full Text PDFSci Total Environ
October 2022
Key Laboratory of the Three Gorges Reservoir Region's Eco-Environment, Ministry of Education, Chongqing University, Chongqing 400045, China.; College of Environment and Ecology, Chongqing University, Chongqing 400045, China.. Electronic address:
Removal of phosphorus (P) from wastewater and its recovery as a fertilizer are solutions to both P pollution control and resource recycling for agriculture. In this study, various layered double hydroxide biochar composites (LDH/BCs), namely, Zn-Al-LDH/BC, Mg-Al-LDH/BC, and Mg-Fe-LDH/BC, were synthesized to remove P from secondary effluents and then applied as fertilizers. Batch experiments showed that LDH/BCs could adsorb P in fast kinetics, with adsorption capacities ranging 35.
View Article and Find Full Text PDFSci Total Environ
July 2022
College of Environmental Science and Engineering and Key Laboratory of Environmental Biology and Pollution Control (Ministry of Education), Hunan University, Changsha 410082, PR China. Electronic address:
In this study, CuCo layered double hydroxide/biochar composite (CuCo LDH/BC) was prepared and employed for activating HO to degrade ciprofloxacin (CIP), a common fluroquinolone antibiotic detected in water environment. The as-synthesized catalysts were also comprehensively characterized to study the physiochemical properties. For the catalytic activity, the degradation rate of CuCo LDH/BC to CIP was approximately 1.
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