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Photochemistry and Non-adiabatic Photodynamics of the HOSO Radical. | LitMetric

Hydroxysulfinyl radical (HOSO) is important due to its involvement in climate geoengineering upon SO injection and generation of the highly hygroscopic HSO. Its photochemical behavior in the upper atmosphere is, however, uncertain. Here we present the ultraviolet-visible photochemistry and photodynamics of this species by simulating the atmospheric conditions with high-level quantum chemistry methods. Photocleavage to HO + SO arises as the major solar-induced channel, with a minor contribution of H + SO photoproducts. The efficient generation of SO is relevant due to its reactivity with O and the consequent depletion of ozone in the stratosphere.

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http://dx.doi.org/10.1021/jacs.1c05149DOI Listing

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