A Neutral Beryllium(I) Radical.

Angew Chem Int Ed Engl

Institute for Inorganic Chemistry, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074, Würzburg, Germany.

Published: September 2021

The reduction of a cyclic alkyl(amino)carbene (CAAC)-stabilized organoberyllium chloride yields the first neutral beryllium radical, which was characterized by EPR, IR, and UV/Vis spectroscopy, X-ray crystallography, and DFT calculations.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8518760PMC
http://dx.doi.org/10.1002/anie.202108405DOI Listing

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A Neutral Beryllium(I) Radical.

Angew Chem Int Ed Engl

September 2021

Institute for Inorganic Chemistry, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074, Würzburg, Germany.

The reduction of a cyclic alkyl(amino)carbene (CAAC)-stabilized organoberyllium chloride yields the first neutral beryllium radical, which was characterized by EPR, IR, and UV/Vis spectroscopy, X-ray crystallography, and DFT calculations.

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