AI Article Synopsis

  • Cobalt polyoxometalates (Co-POMs) are effective water oxidation catalysts (WOCs), outperforming iron counterparts while providing clear structures for experimental and computational analysis of oxygen evolution reactions (OER).
  • The study compares the catalytic activity of the tetracobalt Weakley sandwich structure with iron analogs and evaluates how the nuclearity of POMs influences their efficiency.
  • Results show Co-POMs not only exhibit better activity than iron-based ones, but their performance is less affected by structural variations, with similar reaction mechanisms supported by both experimental and computational data.

Article Abstract

Cobalt polyoxometalates (Co-POMs) have emerged as promising water oxidation catalysts (WOCs), with the added advantage of their molecular nature despite being metal oxide fragments. In comparison with metal oxides, that do not offer well-defined active surfaces, POMs have a controlled, discrete structure that allows for precise correlations between experiment and computational analyses. Thus, beyond highly active WOCs, POMs are also model systems to gain deeper mechanistic understanding on the oxygen evolution reaction (OER). The tetracobalt Weakley sandwich [Co (HO)(B-α-PWO)] () has been one of the most extensively studied. We have compared its activity with that of the iron analog [Fe (HO)(B-α-PWO)] () looking for the electronic effects determining their activity. Furthermore, the effect of POM nuclearity was also investigated by comparison with the iron- and cobalt-monosubstituted Keggin clusters. Electrocatalytic experiments employing solid state electrodes containing the POMs and the corresponding computational calculations demonstrate that Co-POMs display better WOC activity than the Fe derivatives. Moreover, the activity of POMs is less influenced by their nuclearity, thus Weakley sandwich moieties show slightly improved WOC characteristics than Keggin clusters. In good agreement with the experimental data, computational methods, including p values, confirm that the resting state for Fe-POMs in neutral media corresponds to the (Fe-OH) species. Overall, the proposed reaction mechanism for is analogous to that found for , despite their electronic differences. The potential limiting step is a proton-coupled electron transfer event yielding the active (Fe[double bond, length as m-dash]O) species, which receives a water nucleophilic attack to form the O-O bond. The latter has activation energies slightly higher than those computed for the Co-POMs, in good agreement with experimental observations. These results provide new insights for the accurate understanding of the structure-reactivity relationships of polyoxometalates in particular, and or metal oxides in general, which are of utmost importance for the development of new bottom-up synthetic approaches to design efficient, robust and non-expensive earth-abundant water oxidation catalysts.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8246111PMC
http://dx.doi.org/10.1039/d1sc01016fDOI Listing

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