"In-situ synthesized" iron-based bimetal promotes efficient removal of Cr(VI) in by zero-valent iron-loaded hydroxyapatite.

Anionic Cr(VI) and cationic heavy metals generally co-exist in industrial effluents and threaten the public health. Zero-valent iron (ZVI) particles tent to passivate rapidly, which results in a gradual drop in its reactivity. In this work, a strategy of "in-situ synthesized" iron-based bimetal was first developed to stimulate the self-activation of passivated ZVI. During this process, ZVI-loaded hydroxyapatite (ZVI/HAP) was prepared to enhance the affinity for co-existing Cu, which promoted the in-situ Cu deposition on ZVI/HAP to form a Fe-Cu bimetal. The deposited Cu significantly decreased the activation energy (E) of Cr(VI) reduction by 24.9%, and its corresponding Cr(VI) removal (96.53%) was much higher that of single Cr(VI) system (68.67%) within 9 h. More importantly, the removal of Cr(VI) and Cu were synchronously achieved. Systematical electrochemical characterizations were first introduced to explore the galvanic behaviors of iron-based bimetal. The charge transfer resistance and the negative open circuit potential of ZVI/HAP significantly decreased with the Cu deposition, thereby accelerating the electron transfer from Fe to Cu. The enhanced electron transfer further facilitated the Fe(II) release to promote Cr(VI) reduction. This "in-situ synthesized" iron-based bimetal strategy provides a novel pattern for ZVI activation and exhibits practical application in remediation of combined contaminant.