Polycyclic aromatic hydrocarbons are a class of persistent organic water pollutants that raise serious concerns owing to their carcinogenicity and other negative impacts on humans and ecosystems. In this study, BiMoO/reduced graphene oxide (rGO) nanocomposites were designed and prepared for the adsorption-assisted photodegradation of naphthalene molecules in an aqueous medium. The synthesized BiMoO nanoplates and BiMoO/rGO nanocomposites were characterized by X-ray diffraction, Fourier transform infrared, scanning electron microscopy, high-resolution transmission microscopy, X-ray photoelectron spectroscopy, ultraviolet spectroscopy, Brunauer-Emmett-Teller, and photoluminescence measurements. The photodegradation of naphthalene molecules was observed to assess the photocatalytic characteristics of the samples under visible light. The BiMoO/rGO nanocomposites exhibited significantly improved photocatalytic efficiency compared to pure BiMoO. Among the nanocomposites, those containing 2 wt % rGO showed the best photocatalytic activity. The incorporation of rGO enhanced the visible light absorption and decreased the recombination rate of photogenerated charge carriers. Moreover, a BiMoO/rGO nanocomposite showed excellent reusability for five cycles.
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http://dx.doi.org/10.1021/acsomega.1c01296 | DOI Listing |
Luminescence
January 2025
Department of Electronics and Communication Engineering, Madan Mohan Malaviya University of Technology, Gorakhpur, Uttar Pradesh, India.
This study focuses on enhancing the performance of photodetector through the utilization of inorganic perovskite material. It emphasizes that the unique properties of perovskite materials contribute to the superior performance of the photodetector. The focus is on the design and enhancement of CsSnI-based photodetector having graphene oxide (GO) and PCBM as charge transport layer, analysing their potential for improved operation.
View Article and Find Full Text PDFChem Commun (Camb)
January 2025
Chemical Sciences Division, Indian Institute of Petroleum, Mohkampur, Dehradun-248005, India.
Expression of concern for 'Graphene oxide: an efficient and reusable carbocatalyst for aza-Michael addition of amines to activated alkenes' by Sanny Verma , , 2011, , 12673-12675, https://doi.org/10.1039/C1CC15230K.
View Article and Find Full Text PDFNat Commun
January 2025
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang, 110016, P. R. China.
With the rapid development of graphene industry, low-cost sustainable synthesis of monolayer graphene oxide (GO) has become more and more important for many applications such as water desalination, thermal management, energy storage and functional composites. Compared to the conventional chemical oxidation methods, water electrolytic oxidation of graphite-intercalation-compound (GIC) shows significant advantages in environmental-friendliness, safety and efficiency, but suffers from non-uniform oxidation, typically ~50 wt.% yield with ~50% monolayers.
View Article and Find Full Text PDFNaunyn Schmiedebergs Arch Pharmacol
January 2025
Neurophysiology Research Center, Cellular and Molecular Medicine Research Institute, Urmia University of Medical Sciences, Urmia, Iran.
Breast cancer (BC) with aggressive metastasis is a serious ongoing public health problem among women. Graphene oxide (GO) has an inhibitory effect on the migration rate and metastasis of BC cells, but its various aspects have not yet been explored. This paper aims to research into the effect of GO nanoparticles (GO-Np) on the migratory behavior of MDA-MB-231 as a metastatic human BC cell line.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
College of Chemical Engineering, Xiangtan University, Xiangtan 411105, China.
The development of all-solid-state frustrated Lewis pairs (FLPs) metal-free hydrogenation catalysts with excellent activity and stability remains a significant challenge. In this work, B, N codoped FLPs catalysts (De-rGO-NB) were prepared by the strategy of fabricating carbon defects and heteroatom doping on the surface of reduced graphene oxide and applied in the selective hydrogenation of α,β-unsaturated aldehydes to unsaturated alcohols. It was found that electron-rich pyridine-N (Lewis base) and adjacent electron-deficient B-N (Lewis acid) sites could be constructed on the surface of reduced graphene oxide using dicyandiamide and metaboric acid as N and B sources, thus forming FLPs sites.
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