Heavy metal contamination in ground dust presents potential environmental and human health threats. However, the heavy metal contamination status of ground dust in the vicinity of public point utilities remains poorly explored. Therefore, this study has been designed to analyze the heavy metal contaminations in the ground dust collected monthly near a public bronze sculpture in an urban campus of Nantong, China, using geo-accumulation indexes (I), enrichment factors (EF), potential ecological risk indexes (RI), and health risks (noncarcinogenic risks (HI) and carcinogenic risks (CR)). This study revealed that the maximum Cr, Cu, Mn, Ni, Pb, and Zn concentrations in ground dust samples were 156.2, 708.8, 869.8, 140.8, 180.5, and 1089.7 mg kg, respectively, in which the mean Cu and Zn concentrations were 9 and 7 times higher than the background level in the soil. Temporally speaking, for the majority of heavy metals (with the exception of Ni), the high-concentration seasons tend to be mainly summer and autumn. It was observed that Cu and Zn exhibited significant enrichment (EF = 11.7 and 8.4, respectively), moderate-to-strong pollution (I = 2.4 and 2.0, respectively), and moderate- and low-potential ecological risks ([Formula: see text] = 45.6 and 6.6, respectively). The noncarcinogenic risks which adults exposed to the heavy metal concentrations suffered were found to be insignificant. However, the carcinogenic risks related to Ni (1.3E-04) had exceeded the acceptable level. Based on principal component analysis (PCA) and correlation analysis, the heavy metal concentrations in the ground dust of urban campuses could be related to public point utilities, traffic-related exhaust sources, and industrial activities. This study's findings demonstrated that urban public utilities require more attention due to their significant enrichment, ecological risk factors, and the significant carcinogenic risks to the population.
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http://dx.doi.org/10.1007/s11356-021-15243-0 | DOI Listing |
3 Biotech
January 2025
Department of Agronomy, Abdul Wali Khan University, Mardan, 23200 Khyber Pakhtunkhwa Pakistan.
Soil contamination with toxic heavy metals [such as aluminum (Al)] is becoming a serious global problem due to the rapid development of the social economy. Although plant growth-promoting rhizo-bacteria (PGPR) are the major protectants to alleviate metal toxicity, the study of these bacteria to ameliorate the toxic effects of Al is limited. Therefore, the present study was conducted to investigate the combined effects of different levels of (5 ppm and 10 ppm) of accession number of MT123456 on plant growth and biomass, photosynthetic pigments, gas exchange attributes, oxidative stress and response of antioxidant compounds (enzymatic and nonenzymatic), and their specific gene expression, sugars, nutritional status of the plant, organic acid exudation pattern and Al accumulation from the different parts of the plants, which was spiked with different levels of Al [0 µM (i.
View Article and Find Full Text PDFLuminescence
January 2025
Vlokh Institute of Physical Optics, Ivan Franko National University of Lviv, Lviv, Ukraine.
Spectroscopic properties of Tb-doped and Tb-Ag codoped lithium tetraborate (LTB) glasses with LiBO (or LiO-2BO) composition are investigated and analysed using electron paramagnetic resonance (EPR), optical absorption, photoluminescence (PL) and photoluminescence excitation (PLE) spectra, PL decay kinetics and absolute quantum yield (QY) measurements. PL spectra of the investigated glasses show numerous narrow emission bands corresponding to the D → F (J = 6-0) and D → F (J = 5-3) transitions of Tb (4f) ions. The most intense PL band of Tb ions at 541 nm (D → F transition) is characterised by a lifetime slightly exceeding 2.
View Article and Find Full Text PDFChem Commun (Camb)
January 2025
School of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, P. R. China.
Neodymium iron boron (NdFeB) magnets are critical components in green energy technologies and have received increasing attention due to the limited availability of the raw materials, specifically rare earth elements (REEs). The supply risks associated with primary mining of RE ores, which have significant environmental impacts, underscore the necessity for recycling RE secondary resources. Waste NdFeB magnets, generated during manufacturing processes and recovered from end-of-life products, represent valuable RE secondary resources.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
The State Key Laboratory of Molecular Engineering of Polymers and Department of Macromolecular Science, Fudan University, Shanghai 200438, P. R China.
Designing artificial enzymes for in vivo catalysis presents a great challenge due to biomacromolecule contamination, poor biodistribution, and insufficient substrate interaction. Herein, we developed single-chain polymeric nanoparticles with Cu/N-heterocyclic carbene active sites (SCNP-Cu) to function as peroxidase mimics for in vivo catalysis and chemo-dynamic therapy (CDT). Compared with the enzyme mimics based on unfolded linear polymer scaffold and multichain cross-linked scaffold, SCNP-Cu exhibits improved tumor accumulation and CDT efficiency both in vitro and in vivo.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Institute of Optical Functional Materials for Biomedical Imaging, School of Chemistry and Pharmaceutical Engineering, Shandong First Medical University & Shandong Academy of Medical Science, Taian, Shandong 271016, PR China.
Photoactivatable gold nanocarriers are transforming antitumor therapies by leveraging their distinctive physicochemical properties, enabling targeted drug delivery and enhanced therapeutic efficacy in cancer treatment. This study systematically investigates how surface topography and morphology of gold nanocarriers influence drug loading capacity, light-to-heat conversion efficiency, and overall therapeutic performance in photo/chemotherapy. We synthesized four distinct morphologies of gold nanoparticles: porous gold nanocups (PAuNCs), porous gold nanospheres (PAuNSs), solid gold nanocups (SAuNCs), and solid gold nanospheres (SAuNSs).
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