Remarkably enhanced ion-exchange capacity of HO-intercalated layered titanate.

Chem Commun (Camb)

School of Materials Science and Engineering, Shaanxi University of Science and Technology, Weiyang, Xi'an, Shaanxi 710021, P. R. China.

Published: July 2021

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H2O2-intercalated layered titanate H1.07Ti1.73O4 (H2O2-HTO) exhibits a dramatically enhanced ion-exchange capacity and remarkably improved reaction rate with various divalent cations. The intercalation can increase the negative charge density of the TiO6 octahedral layer and the number of ion-exchangeable H+ by forming a Ti(iv)-O-O-H bond that is the driving force to change the ion exchange performance.

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http://dx.doi.org/10.1039/d1cc01387dDOI Listing

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