The aim of this study was to analyze the crystallization of the MgZnCa metallic glass alloy. The crystallization process of metallic glass MgZnCa was investigated by means of the differential scanning calorimetry. The glass-forming ability and crystallization are both strongly dependent on the heating rate. The crystallization kinetics, during the isothermal annealing, were modelled by the Johnson-Mehl-Avrami equation. Avrami exponents were from 2.7 to 3.51, which indicates diffusion-controlled grain growth. Local exponents of the Johnson-Mehl-Avrami equation were also calculated. In addition, the Mg phase-being the isothermal crystallization product-was found, and the diagram of the time-temperature phase transformation was developed. This diagram enables the reading of the start and end times of the crystallization process, occurring in amorphous ribbons of the MgZnCa alloy on the isothermal annealing temperature. The research showed high stability of the amorphous structure of MgZnCa alloy at human body temperature.
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http://dx.doi.org/10.3390/ma14133583 | DOI Listing |
Materials (Basel)
October 2024
Department of Engineering Materials and Biomaterials, Silesian University of Technology, 18a Konarskiego Street, 44-100 Gliwice, Poland.
Magnesium-based materials are an interesting solution in terms of medical applications. Alloys that are hard to obtain via standard means may be manufactured via mechanical alloying (MA), which allows the production of materials with complex a chemical composition and non-equilibrium structures. This work aimed to investigate materials obtained by the MA process for 5, 8, 13, and 20 h in terms of their phase composition and changes during heating.
View Article and Find Full Text PDFInt J Mol Sci
May 2024
Department of Industrial Engineering, University of Trento, 38123 Trento, Italy.
Overly fast corrosion degradation of biodegradable magnesium alloys has been a major problem over the last several years. The development of protective coatings by using biocompatible, biodegradable, and non-toxic material such as chitosan ensures a reduction in the rate of corrosion of Mg alloys in simulated body fluids. In this study, chitosan/TiO nanocomposite coating was used for the first time to hinder the corrosion rate of Mg19Zn1Ca alloy in Hank's solution.
View Article and Find Full Text PDFColloids Surf B Biointerfaces
June 2024
Research Center for Nano-Biomaterials & Regenerative Medicine, Department of Biomedical Engineering, College of Biomedical Engineering, Taiyuan University of Technology, Taiyuan 030024, China; Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering, Taiyuan 030060, China. Electronic address:
In the field of orthopedics, it's crucial to effectively slow down the degradation rate of Mg alloys. This study aims to improve the degradation behavior of Mg-Zn-Ca alloys by electrodepositing fluorohydroxyapatite (FHA). We investigated the microstructure and bond strength of the deposition, as well as degradation and cellular reactions.
View Article and Find Full Text PDFJ Mater Sci Mater Med
March 2024
Jiangsu Key Laboratory for Advanced Metallic Materials, School of Materials Science and Engineering, Southeast University, Nanjing, 211189, China.
Biodegradable porous Mg scaffolds are a promising approach to bone repair. In this work, 3D-spherical porous Mg-1.5Zn-0.
View Article and Find Full Text PDFACS Biomater Sci Eng
November 2023
Department of Periodontics and Oral Biology, School of Stomatology, China Medical University, Liaoning 110002, China.
Degradability is vital for bone filling and plays an important role in bone regeneration. Evidence indicates that apatite-based calcium phosphate cement (ACPC) is a prospective biomaterial for bone repair with enhanced osteogenesis. However, poor degradability restricts their clinical application.
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